Carbonylation process for the production of aromatic acids and d

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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560100, 560105, 562406, 564180, 564183, 564166, 568 38, 546298, 549 71, 549 72, 549505, 549506, C07C 6976

Patent

active

045074933

ABSTRACT:
The present invention provides a process for the preparation of aryl carboxylic acids and derivatives thereof by the carbonylation of aryl sulfonyl chlorides. The aryl sulfonyl chlorides are reacted with carbon monoxide and water or an alcohol or amine in the presence of a zero-valent metal catalyst consisting essentially of palladium.

REFERENCES:
patent: 3700729 (1971-10-01), Fenton
patent: 3769326 (1973-10-01), Paulik et al.
patent: 3887595 (1975-06-01), Nozaki
patent: 3965132 (1976-06-01), Norell

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