Carbonylation of olefinically unsaturated compounds

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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252431N, 2603436, 260429R, 260439R, 2604651, 2604654, 2604656, 560204, 568455, B01J 3120, B01J 3128, B01J 3106, C07C12138

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042357446

ABSTRACT:
Oxygenated organic compounds, e.g. esters, aldehydes, and amides, are prepared by reacting an olefinically unsaturated compound with carbon monoxide and a compound containing a replaceable hydrogen atom in the presence of a catalyst comprising cobalt and/or ruthenium carbonyl and a polyamine promoter ligand. These reactions are carried out under relatively mild conditions of temperature and pressure.

REFERENCES:
patent: 3594425 (1971-07-01), Brader, Jr.
patent: 3931332 (1976-01-01), Wilkes
patent: 4045492 (1977-08-01), Kniese et al.
patent: 4060543 (1977-11-01), Weitz et al.

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