Carbonylation of mercaptans

Details Carbonylation of mercaptans Carbonylation of mercaptans

1986-06-03

1987-11-10

Schwartz, Richard A.

Organic compounds -- part of the class 532-570 series

Organic compounds

Esters having the thiocarboxylate group, -cx-, wherein the...

558250, C07C153017, C07C153023

Patent

active

047058803

ABSTRACT:
Thioesters of the formula RCOSR are produced from a mercaptan of the formula RSH wherein R is a benzylic, aromatic or aliphatic moiety by reacting the mercaptan with carbon monoxide in the presence of a polyunsaturated olefinic hydrocarbon and as catalyst a metal component selected from iron, cobalt, nickel, molybdenum, ruthenium, rhodium and iridium, the metal component being in free or combined form.

REFERENCES:
patent: 3933884 (1976-01-01), Knifton

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