Carbonylation of alkanols

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 6800

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active

043604773

ABSTRACT:
Alkanols can be carbonylated with carbon monoxide and oxygen at elevated temperatures in the presence of certain copper salts to form dialkyl carbonates. The invention also covers the carbonylation by recycling of the azeotropic mixture of methanol and the corresponding dimethyl carbonate.

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patent: 3980690 (1976-09-01), Cipriani et al.
patent: 4131521 (1978-12-01), Cipris et al.
patent: 4218391 (1980-08-01), Romano et al.

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