Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component
Patent
1993-11-05
1996-06-04
Lewis, Michael
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Sulfur or sulfur containing component
423224, 423DIG19, B01D 5348
Patent
active
055230695
ABSTRACT:
A method for removing carbonyl sulfide from fluids, particularly gases, involves contacting them with alkaline aqueous solutions containing peroxide and hindered amine. The sulfur products so formed can then be separated from the fluid. In one embodiment, gas containing carbonyl sulfide is cycled through a wet scrubber containing a solution of hydrogen peroxide and methyldiethanolamine, triethylamine, dimethylmonoethanolamine, diethylmonoethanolamine, triethanolamine, 2-amino-2-meth-yl-1-propanol, and/or 1,8-p-menthanediaminemethyldiethanolamine at a pH of about 9 to 11, e.g., about 10. Methyldiethanolamine is preferred in one embodiment. A dispersant such as a water-soluble polymer having a molecular weight of about 500 to 100,000 may optionally be employed in the solution. Abatement of greater than 90% of the carbonyl sulfide is achieved in preferred embodiments.
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DiMauro Peter T.
Lewis Michael
Nalco Fuel Tech
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