Carbonaceous material for production of hydrogen from low heatin

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Inorganic carbon containing

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48197R, 48203, 423459, 4236481, 502438, B01J 2118, C01B 3102, C01B 302, C10K 304

Patent

active

048732141

ABSTRACT:
A process for the catalytic production of hydrogen, from a wide variety of low heating value fuel gases containing carbon monoxide, comprises circulating a carbonaceous material between two reactors--a carbon deposition reactor and a steaming reactor. In the carbon deposition reactor, carbon monoxide is removed from a fuel gas and is deposited on the carbonaceous material as an active carbon. In the steaming reactor, the reactive carbon reacts with steam to give hydrogen and carbon dioxide. The carbonaceous material contains a metal component comprising from about 75% to about 95% cobalt, from about 5% to about 15% iron, and up to about 10% chromium, and is effective in suppressing the production of methane in the steaming reactor.

REFERENCES:
patent: 4591334 (1986-05-01), Brooks
patent: 4642125 (1987-02-01), Burk et al.
patent: 4650657 (1987-03-01), Brooks

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