Carbonaceous electrode material for secondary battery and proces

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

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429217, 429232, 264105, 252502, 252510, 423448, 423450, 423460, H01M 458, C01B 3104, H01B 104, C04B 3500

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055276431

ABSTRACT:
A non-aqueous solvent-type secondary battery having a large charge-discharge capacity and exhibiting a high utilization rate of an active substance, such as lithium, and an excellent charge-discharge cycle characteristic, can be constituted by using a carbonaceous electrode material having a specific microtexture. The carbonaceous electrode material is characterized by having an average (002)-plane spacing d.sub.002 of 0.336-0.375 nm and a crystallite size in c-axis direction Lc.sub.(002) of at most 50 nm, respectively, as measured by X-ray diffraction method, and an optically anisotropic texture showing a fine mosaic texture when observed through a polarizing microscope. The carbonaceous material may suitably be produced through a process including the steps of: crosslinking a tar or pitch of a petroleum or coal origin, and carbonizing the crosslinked tar or pitch at a temperature of at least 800.degree. C. under a reduced pressure or in an inert gas atmosphere.

REFERENCES:
patent: 3909449 (1975-09-01), Nagai et al.
patent: 4945014 (1990-07-01), Miyabayashi et al.
patent: 5340670 (1994-08-01), Takami et al.
Patent Abstracts of Japan, vol. 10, No. 258 (C-370) 4 Sep. 1986 & JP-A-61 083 611 (Mitsubishi Petrochem Co., Ltd.) 28 Apr. 1986.
Database WPI, Week 9432, Derwent Publications Ltd., London, GB; AN 94-258102 & JP-A-6 187 991 (Osaka Gas Co., Ltd.) 8 Jul. 1994.
Database WPI, Week 9432, Derwent Publications Ltd., London, GB; AN 94-258086 & JP-A-6 187 972 (Osaka Gas Co., Ltd.) 8 Jul. 1994.
Patent Abstracts of Japan, vol. 18, No. 139 (E-1519) 8 Mar. 1994 & JP-A-05 325 948 (Osaka Gas Co., Ltd.) 10 Dec. 1993.

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