Liquid purification or separation – Processes – Ion exchange or selective sorption
Reexamination Certificate
2001-12-24
2004-11-30
Hopkins, Robert A. (Department: 1724)
Liquid purification or separation
Processes
Ion exchange or selective sorption
C210S664000, C210S679000, C423S447300, C428S408000
Reexamination Certificate
active
06824689
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to structures containing carbon nanotubes, methods of making structures containing carbon nanotubes on porous substrates, and processes using carbon nanotube-containing structures.
INTRODUCTION
Carbon nanotubes, graphite-like sheets rolled up in coaxial cylinders, have been studied intensively since their discovery in 1991. Nanotubes were found in single sheet wall or multi-wall form with diameters of 3-100 nm and up to 200 &mgr;m long. These new carbon materials have many unusual and potentially valuable properties, such as highly anisotropic (i.e., directional) thermal conductivity. However, the reactivities of these materials in novel combinations and the synthesis of these materials in novel combinations with varying substrates, coatings, etc., cannot be predicted.
Techniques for growing carbon nanotubes on some substrates are known. Moskovits et al., in U.S. Pat. No. 6,129,901, have reported the growth of carbon nanotubes on anodized aluminum. Xie et al., in Advanced Materials vol. 11, pp 1135-1138 (1999), reported that mesoporous silica can be used to produce well-aligned carbon nanotubes. It appears from the paper of Xie et al. that drying of the mesoporous silica results in cracking into powders or particles with surface dimensions of a few square millimeters.
SUMMARY OF THE INVENTION
In a first aspect, the invention provides an engineered catalyst that includes a support material having through-porosity (defined as discussed below), a layer comprising carbon nanotubes on the support material; and a surface-exposed catalytically-active composition.
In another aspect, the invention provides catalyst including a support; nanotubes dispersed over the support; and a catalytically-active composition dispersed over the nanotubes.
In yet another aspect, the invention provides a method of forming a porous carbon nanotube containing catalyst structure. In this method, a large pore support is provided having through porosity. Carbon nanotubes are formed over the large pore support, and a catalyst composition is deposited over the carbon nanotubes.
The invention also includes methods of conducting catalyzing chemical reactions in which one or more reactants are contacted with any of the carbon nanotube containing catalysts described herein. In this method, the one or more reactants react to form a product. The catalyst catalyzes the reaction relative the same reaction conducted in the absence of a catalyst. For example, the invention provides a Fischer-Tropsch process in which a gaseous composition, comprising CO and hydrogen, is passed over any of the carbon nanotube containing catalysts described herein.
The invention also provides a catalytic process for aqueous phase hydrogenations to produce higher value chemical products from biomass feedstock.
In another aspect, the invention provides a process of making a porous, carbon nanotube-containing structure, comprising: providing a support material having through-porosity; depositing seed particles on the support material to form a seeded support material; and heating the support material and simultaneously exposing the seeded support to a carbon nanotube precursor gas to grow carbon nanotubes on the surface of the seeded support material.
In another aspect, the invention provides a porous carbon-nanotube-containing structure that includes a large pore support having through porosity; and carbon nanotubes disposed over the large pore support.
In still another aspect, the invention provides a method of making a carbon-nanotube-containing structure in which a surfactant template composition (a composition containing a surfactant and silica or silica precursors) is applied onto a support. Carbon nanotubes are then grown over the layer made from the surfactant template composition.
The invention also provides processes of using carbon nanotube-containing structures. Preferably, any of the carbon nanotube-containing structures described herein can be used in processes or devices including: catalysis, adsorption, ion exchange, separation of chemical components, filtration, storage of gases (for example, hydrogen or carbon dioxide), distillation (including reactive distillation), a support structure for chemical, including biological, sensors, a support structure to immobilize proteins for bioprocessing, and a component in a heat exchanger. Features of carbon nanotube-containing structures that make these structures particularly advantageous include: high surface area, excellent thermal conductivity, capillary force for enhanced condensation, and good attractive force for certain organic species.
Thus, the invention provides a method of adsorbing a chemical component in which a chemical component is contacted with a carbon nanotube-containing structure and the chemical component is adsorbed on the surface of the carbon nanotube-containing structure. A preferred chemical species is hydrogen. In a preferred embodiment, the exterior surface of the carbon nanotube-containing structure is a palladium coating. In preferred embodiments, the adsorption is run reversibly in a process such as pressure swing or temperature swing adsorption. This method is not limited to adsorbing a single component but includes simultaneous adsorption of numerous components.
Similarly, the invention provides a method of separating a chemical component from a mixture of components. “Mixture” also includes solutions, and “separating” means changing the concentration of at least one component relative to the concentration of at least one other component in the mixture and preferably changes the concentration of at least one component by at least 50% (more preferably at least 95%) relative to at least one other component, for example, reducing the concentration of a 2M feed stream to 1M or less. Particular types of separations include filtration, selective adsorption, distillation and ion exchange. Filtering can be accomplished, for example, by passing a mixture having at least two phases through a porous carbon nanotube-containing structure where at least one of the phases gets physically caught in the structure. A carbon nanotube-containing structure with surface-exposed carbon nanotubes can function efficiently for the separation of some organics because the nanotubes can be hydrophobic while organics can be adsorbed quite well. For ion exchange it is desirable to coat the surface with an ion exchange agent.
The preparation of porous materials, such as foams, coated with carbon nanotubes and a high-surface area metal oxide coating, can be difficult. The locally aligned nanotubes exhibit high surface Van der Waal forces and hydrophobic properties. Conventional wash coating of metal oxides using aqueous based solution often results in a non-uniform coating or poor adhesion onto the nanotubes. We have developed treatment methods to modify the surface properties of the nanotubes, making this new class of materials possible for a variety of important industrial applications such as engineered catalyst structures. The invention has particular utility in the chemical (including biological), fossil fuel, automotive, and environmental industries. For example, we have fabricated a carbon nanotube-based engineered catalyst and have demonstrated its performance for Fisher-Tropsch reaction in a microchannel reactor. Under operating conditions typical of microchannel reactors with minimal heat and mass transfer limitations, it was found that the integrated nanotube structure has further improved the performance, as indicated by enhanced reaction rate and improved product selectivity. This concept can also be applied toward conventional reactors, which operate under severe heat and mass transfer inhibitions with catalyst performance far less than that predicted from the intrinsic kinetics.
Various embodiments of the present invention can offer numerous advantages, including: creating larger pores through which flow occurs, improved heat transport, controlling the direction of heat transport, enhanced surface area, excellent th
Aardahl Christopher L.
Chin Ya-Huei
Gao Yufei
Stewart Terri L.
Wang Yong
Battelle (Memorial Institute)
Hopkins Robert A.
Rosenberg Frank S.
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