Carbon monoxide sensor and method of use thereof

Chemical apparatus and process disinfecting – deodorizing – preser – Analyzer – structured indicator – or manipulative laboratory... – Means for analyzing gas sample

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C422S083000, C436S134000, C436S149000, C438S048000, C438S049000, C438S142000, C029S592100, C257S213000, C257S252000, C257S253000

Reexamination Certificate

active

10387921

ABSTRACT:
Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

REFERENCES:
patent: 4058368 (1977-11-01), Svensson et al.
patent: 4324760 (1982-04-01), Harris
patent: 4514263 (1985-04-01), Janata
patent: 4613422 (1986-09-01), Lauks
patent: 5250171 (1993-10-01), Warburton et al.
patent: 5279795 (1994-01-01), Hughes et al.
patent: 5367283 (1994-11-01), Lauf et al.
patent: 5417821 (1995-05-01), Pyke
patent: 5439580 (1995-08-01), Akbar et al.
patent: 5576067 (1996-11-01), Miyayama et al.
patent: 5650054 (1997-07-01), Shen et al.
patent: 5897766 (1999-04-01), Kawatsu
patent: 6001499 (1999-12-01), Grot et al.
patent: 6041643 (2000-03-01), Stokes et al.
patent: 6254749 (2001-07-01), Yokota et al.
patent: 6293137 (2001-09-01), Liu et al.
patent: 6316133 (2001-11-01), Bossel
patent: 6368479 (2002-04-01), Yokota et al.
patent: 6429019 (2002-08-01), Goldstein et al.
patent: 2006/0196246 (2006-09-01), Li et al.
Tracy, J. C.; Palmberg, P. W.: “Structural Influences on Adsorbate Binding Energy. I. Carbon Monoxide on (100) Palladium,”The Journal of Chemical Physics, V.51, pp. 4852-4862 (1969).
Conrad, H.; Ertl, G.; Koch, J.; Latta, E. E.; “Adsorption of CO on Pd Single Crystal Surfaces,”Surface Science 43, pp. 462-480 (1974).
Bradshaw, A. M.; Hoffmann, F. M.; “The Chemisorption of Carbon Monoxide on Palladium Single Crystal Surfaces: IR Spectroscopic Evidence for Localised Site Adsorption,”Surface Science 72, pp. 513-535 (1978).
Lundstrom, I.; “Hydrogen Sensitive MOS-Structures Part I: Principles and Applications,”Sensors and Actuators, 1, pp. 403-426 (1981).
Lundstrom, I.; Soderberg, D.; “Hydrogen Sensitive MOS-Structures Part 2: Characterization,”Sensors and Actuators 2, pp. 105-138 (1981/82).
Kok, G. A.; Noordermeer, A.; Nieuwenhuys, B. E.; “Decomposition of Methanol and the Interaction of Coadsorbed Hydrogen and Carbon Monoxide on a Pd(111) Surface,”Surface Science 135, pp. 65-80 (1983).
Noordermeer, A.; Kok, G. A.; Nieuwenhuys, B. E.; “A Comparative Study of the Behaviour of the PdAg(111) and Pd(111) Surfaces Towards the Interaction with Hydrogen and Carbon Monoxide,”Surface Science 165, pp. 375-392 (1986).
Bastasz, R.; Hughes, R. C.; “Hydrogen particle diagnostic based on Pd-MOS diode arrays,”Rev. Sci.Instrum. 59, pp. 184-186 (1988).
Ratajczykowa, I.; “The Influence of CO on Hydrogen Sorption by Pd(111) Single Crystals,”Surface Science 172, pp. 691-714 (1986).
Hughes, R. C.; Bastasz, R.; “Low-energy proton detection by Pd metal-insulator-semiconductor diodes,”Journal of Applied Physics 64, pp. 6839-6844 (1988).
Hughes, R. C.; Taylor, P. A.; Ricco, A. J., Rye, R. R.; “Kinetics of Hydrogen Adsorption and Absorption: Catalytic Gate MIS Gas Sensors on Silicon,”Journal of Electrochemical Soc., V. 136, No. 9, pp. 2653-2661 (1989).
Fogelberg, J.; Petersson, L.-G.; “Kinetic modelling of the H2-O2reaction on Pd and of its influence on the hydrogen response of a hydrogen sensitive Pd metal-oxide-semiconductor device,”Surface Science 350, pp. 91-102 (1996).
Eriksson, M.; Ekedahl, L.-G.; “The influence of CO on the response of hydrogen sensitive Pd-MOS devices,”Sensors and Actuators B42, pp. 217-223 (1997).
Johansson, M.; Lundstrom, I.; Ekedahl, L.-G.; “Bridging the pressure gap for palladium metal-insulator-semiconductor hydrogen sensors in oxygen containing environments,”Journal of Applied Physics, v.84, No. 1, pp. 44-51 (1998).
Eriksson, M.; Ekedahl, L.-G.; “Real time measurements of hydrogen desorption and absorption during CO exposures of Pd: hydrogen sticking and dissolution,”Applied Surface Science, pp. 89-97 (1998).
Eriksson, M.; Ekedahl, L.-G.;“The catalytic oxidation of CO on polycrystalline Pd: experiments and kinetic molding,”Surface Science 412/413, pp. 430-440 (1998).
Hara, S.; Sakaki, K.; Itoh, N.; “Decline in Hydrogen Permeation Due to Concentration Polarization and CO Hindrance in a Palladium Membrane Reactor,”Ind. Eng. Chem. Res., pp. 4913-4918 (1999).
Amandusson, H.; Ekedahl, L.-G.; Dannetun, H.; “The effect of CO and O2on hydrogen permeation through a palladium membrane,”Applied Surface Science 153, pp. 259-267 (2000).
Monnier, J. R.; Medlin, J. W.; Kuo, Y.-J.; “Selective isomerization of 2,5-dihydrofuran to 2,3-dihydrofuran using CO-modified, supported Pd catalysts,”Applied Catalysis A: General, pp. 463-474 (2000).
Pyke, S. C.; Sadwick, L.; “Gallium Nitride Integrated Gas/Temperature Sensors for Fuel Cell System Monitoring for Hydrogen and Carbon Monoxide,”Proceedings of the 2002 U. S. DOE Hydrogen Program Review, pp. 1-11 (2000).
Medlin, J.W.; McDaniel, A.H.;Allendorf, M.D.; Bastasz, R.: “Effects of competitive carbon monoxide adsorption on the hydrogen response of metal-insulator-semiconductor sensors: the role of metal film morphology,”Journal of Applied Physicsv.93(4), pp. 2267-2274, Feb. 15, 2003.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Carbon monoxide sensor and method of use thereof does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Carbon monoxide sensor and method of use thereof, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Carbon monoxide sensor and method of use thereof will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3755206

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.