Carbon fabrics sequentially resin coated with (1) a metal-contai

Stock material or miscellaneous articles – Structurally defined web or sheet – Discontinuous or differential coating – impregnation or bond

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156 60, 156245, 156281, 264 295, 4234472, 427203, 427228, 428246, 428263, 428265, 428272, 428283, 428285, 428328, 428408, B29C 2500, B32B 900, B32B 3126

Patent

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043212980

ABSTRACT:
A fibrous carbon material is first coated with a thermosetting material which remains flexible after being subjected to curing temperatures. The thermosetting material contains a refractory metal capable of reacting with boron to form a metal boride. This thermosetting resin is then cured. The fibrous carbon material is then impregnated with a second thermosetting resin containing a boron compound and, optionally, a refractory metal capable of reacting with boron to form a metal boride. The second thermosetting resin is at least partially cured and a plurality of layers of the fibrous material is then assembled to form a laminate. The laminate is heated to a temperature sufficient to carbonize the thermosetting resin. The resultant carbon-carbon composite has better oxidation resistance, improved high temperature stability, higher density and improved interlaminar tensile strength than does a composite prepared without the presence of the refractory metal in the thermosetting resin.

REFERENCES:
patent: 3672936 (1972-06-01), Ehrenreich
patent: 4087482 (1978-05-01), Shaffer
patent: 4101354 (1978-07-01), Shaffer
patent: 4185043 (1980-01-01), Shaffer

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