Carbon dioxide compatible non-aqueous crosslinked fracturing...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

Reexamination Certificate

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C536S123100, C536S090000, C536S095000, C536S096000, C536S084000, C536S085000, C507S213000, C507S200000, C507S100000, C166S170000, C166S294000, C166S295000, C424S659000, C424S660000, C514S839000, C514S054000

Reexamination Certificate

active

07049436

ABSTRACT:
Alcohol based hydraulic fracturing fluids useful for treating oil and gas wells are disclosed. The fluids are compatible with carbon dioxide, and comprise an alcohol, a polymer, a crosslinking agent, and a breaker. Hydroxypropyl guar with a molar substitution of about 1.2 to about 2.2 is identified as a presently preferred polymer.

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Malone, “Fracturing with crosslinked methanol in water-sensitive formations,” Society of Petroleum Engineers(SPE 70009), 200 pp. 1-7.
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The Journal of Canadian Petroleum Technology, Dec. 1996, vol. 35, No. 10; “Water and Hydrocarbon Phase Trapping in Porous Media-Diagnosis, Prevention and Treatment”.
SPE 22800—Society of Petroleum Engineers, 1992; “New Continuous-Mix Process for Gelling Anhydrous Methanol Minimizes Hazards;” J.E. Thompson, Jr., SPE, BJ Services, Cam McBAin, SPE, Union Pacific Resources Inc., and Garth Gregory and Doug Gerbrandt, BJ Services.

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