Carbene donor-modified Ziegler-Natta catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

Reexamination Certificate

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C502S123000, C526S131000

Reexamination Certificate

active

07078362

ABSTRACT:
A modified Ziegler-Natta catalyst system comprising a titanium or vanadium compound, a magnesium compound, a carbene donor, and an aluminum compound is disclosed. The invention includes a process which comprises polymerizing an alpha-olefin in the presence of the carbene-modified Ziegler-Natta catalyst system. The carbene donor may be used as either an internal or external donor. The use of carbene donors in Ziegler-Natta catalyzed olefin polymerizations should improve catalyst activity and/or stereospecificity.

REFERENCES:
patent: 4136243 (1979-01-01), Appleyard et al.
patent: 4927797 (1990-05-01), Ewen
patent: 5968865 (1999-10-01), Wilson et al.
patent: 6060568 (2000-05-01), Cavell et al.
patent: 6121473 (2000-09-01), Schrock et al.
patent: 6228792 (2001-05-01), Carney
patent: 6436864 (2002-08-01), Tagge
patent: 6525125 (2003-02-01), Giardello et al.
patent: 6576724 (2003-06-01), Olivier-Bourbigou et al.
patent: 6667269 (2003-12-01), Olivier-Bourbigou et al.
patent: 6753378 (2004-06-01), Kojoh et al.
patent: 6794534 (2004-09-01), Grubbs et al.
patent: 6831032 (2004-12-01), Spaether
patent: 2004/0192664 (2004-09-01), Kunz et al.
G. Britovsek et al.,Angew, Chem. Int. Ed. 38(1999) 428.
V. Reimer et al.,Inorg. Chim. Acta 345(2003) 221.
H. Aihara et al.,Chem. Commun.(2003) 2204.
M. Niehues et al.,J. Organometal. Chem. 663(2002) 192.
W. Kirmse,Angew. Chem. Int. Ed. 43(2004) 1767.
N. Kuhn et al.,Inorg. Chim. Acta 238(1995) 179.
W. Herrmann,Angew. Chem. Int. Ed. 41(2002) 1290.
M. Neihues,Organometallics 21(2002) 2905.

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