Captive droplet interfacial tensiometer and methods of use there

Measuring and testing – Liquid analysis or analysis of the suspension of solids in a... – Surface tension

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G01N 1302

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active

053947401

ABSTRACT:
A method and an apparatus for determining the interfacial or surface tension, static or dynamic, between two liquids or between a gas and a liquid under conditions of varying temperature and pressure; and a method for adjusting the interfacial or surface tension in a petroleum reservoir for enhanced oil recovery. A tensiometer is provided which is capable of measuring interfacial or surface tension under pressure and temperature conditions which simulate those present in an actual petroleum reservoir. Measuring the interfacial and surface tension values under actual reservoir conditions then enables the selection of surfactants and other materials for adjusting the interfacial and surface tension to desired values for optimizing the enhanced oil recovery from that reservoir. A tensiometer is provided which includes a calibration body which is imaged along with the image of the test droplet in the tensiometer chamber. This imaging of both the calibration body and the test droplet provides the capability of correction of distortions in the image due to the nature of the chamber window for high pressure and/or high temperature measurements. The tensiometer is also provided with a surface against which the test droplet is imaged and measured, which is an annealed ionomer polymer coating on a polymer surface.

REFERENCES:
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patent: 5031449 (1991-07-01), Kuwana et al.
Egon Matjevic (Editor); Surface and Colloid Science; "Surface Tension. Part II. The Measurement of Surface Tension" by J. F. Paddy; (1969) vol. 1; pp. 101-149.
Laurier L. Schramm (Editor); Emulsions, Fundamentals and Applications in the Petroleum Industry; Chapter 7: "Emulsions in Enhanced Oil Recovery" by Kevin C. Taylor and Blaine F. Hawkins; American Chemical Society, Washington (1992) pp. 263-293.
B. Hawkins, K. Taylor and H. Nasr-El-Din; "Mechanisms of Surfactant and Polymer Enhanced Alkaline Flooding: Application to David Lloydminster and Wainwright Sparky Fields"; Petroleum Society of CIM and AOSTRA; CIM/AOSTRA 1991 Technical Conference in Banff, Apr. 21-24, 1991, pp. 28-1 through 28-16.
H. A. Nasr-El-Din and B. F. Hawkins; "Recovery of Waterflood Residual Oil Using Alkali, Surfactant and Polymer Slugs in Radial Cores"; Revue de L'Institut Francais du Petrole (1991) vol. 46, pp. 199-219.
J. F. Boyce, S. Schurch, Y. Rotenberg and A. W. Neumann; "The Measurement of Surface and Interfacial Tension by the Axisymmetric Drop Technique"; Colloids and Surfaces (1984) vol. 9, pp. 307-317.
J. D. Malcolm and C. D. Elliott; "Interfacial Tension from Height and Diameter of a Single Sessile Drop or Captive Bubble"; The Canadian Journal of Chemical Engineering (Apr. 1980) vol. 58, pp. 151-153.
E. Lefebvre du Prey; "Methode D'interpretation de la Goutte Posee Pour Mesurer la Tension Interfaciale et L'angle de Contact"; Revue de L'institut Francais du Petrole (Mar. 1968) pp. 365-373.

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