Capacitor element having a contact hole structure in an...

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Reexamination Certificate

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C257S532000

Reexamination Certificate

active

06583492

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a semiconductor device and, more particularly, to electrode structure comprising upper and lower layers that are superposed on another, and to a contact hole structure in the electrode structure.
2. Description of the Prior Art
In recent years, semiconductor devices having an increased number of functions have been developed and a demand has arisen for heterogeneous devices in which a memory circuit and a logic circuit or an analog circuit are integrated at a high density with accuracy. Capacitor elements formed with higher density and higher precision are necessary, for example, for analog circuits in such heterogeneous devices. Also, it is necessary to mount a boosting circuit in a nonvolatile semiconductor storage device such as an electrically erasable programmable read-only memory (EEPROM) or a flash memory. A capacitor element of a large area is required as a component of a charge pump circuit constituting the boosting circuit. It is necessary to construct such a capacitor element in such a manner that electrode layers are laid one on another to form opposed electrodes, and each of the opposed electrodes is connected to wiring via a contact hole.
Various techniques, e.g., those disclosed in Japanese Patent Laid-open Publication Nos. 11-30774 and 10-004179 have been proposed as a method for forming the capacitor element in the above-described flash memory. Such conventional techniques will be described with reference to
FIGS. 4
,
5
, and
6
. In these figures, a lower layer electrode compared with an electrode in accordance with the present invention is indicated by hatching to be clearly recognized.
FIGS. 4A and 4B
are a plan view and a cross-sectional view, respectively, of a first example of the conventional capacitor element. The cross-sectional view of
FIG. 4B
is taken along the line X
1
-X
2
in FIG.
4
A.
As shown in
FIGS. 4A and 4B
, an element separation insulating film
101
is formed on a silicon substrate
100
, and a lower layer electrode
102
is formed by patterning on the element separation insulating film
101
. The lower layer electrode
102
is formed from polycrystalline silicon containing an impurity. A capacitor insulating film
103
is formed on the surface of the lower layer electrode
102
. An upper layer electrode
104
is formed by patterning so as to cover the lower layer electrode
102
and the capacitor insulating film
103
. The upper layer electrode
104
is also formed from polycrystalline silicon containing an impurity.
An interlayer insulating film
105
is then deposited on the entire surface by chemical vapor deposition (CVD) and the surface of the insulating film
105
is flattened by chemical mechanical polishing (CMP). A lower layer electrode contact hole
106
is formed in a predetermined region of the interlayer insulating film
105
. A plurality of upper layer electrode contact holes
107
and
107
a
are also formed, as shown in
FIGS. 4A and 4B
. Specifically, the upper layer electrode contact holes
107
and
107
a
are formed in the region right above the lower layer electrode
102
.
Plugs (not shown) are formed so as to fill the lower layer electrode contact hole
106
and the upper layer electrode contact holes
107
and
107
a
and are electrically connected to wiring points (not shown), thus forming the capacitor element.
FIGS. 5A and 5B
are a plan view and a cross-sectional view, respectively, of a second example of the conventional capacitor element. The cross-sectional view of
FIG. 5B
is taken along the line Y
1
-Y
2
in
FIG. 5A. A
major difference of the second example of the conventional capacitor element from the first example resides in that a silicide is formed as a low-resistance portion in the surface of the above-described upper layer electrode of the first example.
FIG. 6
schematically shows in section the structure of a floating-gate MOS transistor and an ordinary MOS transistor for explanation of this silicification.
As shown in
FIGS. 5A and 5B
, an element separation insulating film
201
is formed on a silicon substrate
200
and a lower layer electrode
202
is formed by patterning, as in the first example of the conventional capacitor element. The lower layer electrode
202
is formed from polycrystalline silicon containing an impurity, and a silicide layer
202
a
is formed as a portion of the lower layer electrode
202
. A capacitor insulating film
203
is formed on the surface of the lower layer electrode
202
. An upper layer electrode
206
is formed in a multilayer structure such that a polycrystalline silicon layer
204
and a silicide layer
205
are formed by patterning so as to cover the lower layer electrode
202
and the capacitor insulating film
203
. A side wall insulating film
207
is formed on patterned ends of the upper layer electrode
206
. This side wall insulating film
207
is formed of a silicon oxidation film. A side wall insulating film
208
is formed on stepped portions of the polycrystalline silicon layer
204
formed at ends of the lower layer electrode
202
, as shown in FIG.
5
B. The formation of the silicide layer and the side wall insulating films will be described in detail with reference to FIG.
6
.
An interlayer insulating film
209
is formed on the entire surface, as is that in the first example of the conventional capacitor element. Further, a lower layer electrode contact hole
210
is formed in a predetermined region of the interlayer insulating film
209
. A plurality of upper layer electrode contact holes
211
and
211
a
are also formed, as shown in
FIGS. 5A and 5B
. Specifically, the upper layer electrode contact holes
211
and
211
a
are formed off the region right above the lower layer electrode
202
.
Plugs are formed so as to fill the lower layer electrode contact hole
210
and the upper layer electrode contact holes
211
and
211
a
and are electrically connected to wiring points, as are those in the first example of the conventional capacitor element. The second example of the conventional capacitor element is thus formed.
The above-mentioned silicification will next be described.
FIG. 6
schematically shows in section the structure of a floating-gate MOS transistor and an ordinary MOS transistor. The capacitor element shown in
FIGS. 5A and 5B
is formed on the silicon substrate simultaneously with the floating-gate MOS transistor and the ordinary MOS transistor shown in FIG.
6
.
That is, device separation insulating film
201
is formed on silicon substrate
200
, and a floating-gate electrode
212
is formed in the floating-gate MOS transistor with an tunnel oxide film interposed between the substrate and the floating-gate electrode
212
. A polycrystalline silicon layer
213
is formed on the floating-gate electrode
212
with an interelectrode insulating film interposed therebetween, and a silicide layer
214
is formed on the polycrystalline silicon layer
213
. The polycrystalline silicon layer
213
and the silicide layer
214
forms for a control gate electrode
215
. A side wall insulating film
216
is formed on side wall surfaces of the floating-gate electrode
212
and the control gate electrode
215
. The electrodes, etc., are thus constructed. Further, a diffusion layer
217
for forming source and drain regions of the floating-gate MOS transistor is formed and a silicide layer
218
is formed in an upper portion of the diffusion layer
217
.
Similarly, in the ordinary MOS transistor, a polycrystalline silicon layer
220
is formed on a gate insulating film
219
and a silicide layer
221
is formed in an upper portion of the polycrystalline silicon layer
220
. The polycrystalline silicon layer
220
and the silicide layer
221
form a gate electrode
222
. A side wall insulating film
223
is formed on side wall surfaces of the gate electrode
222
. Further, a diffusion layer
224
for forming source and drain regions of the MOS transistor is formed and a silicide layer
225
is formed in an upper portion of the diffusion la

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