Caged caboxyl compounds and use thereof

Details Caged caboxyl compounds and use thereof Caged caboxyl compounds and use thereof

1995-03-08

1996-12-24

Geist, Gary

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

560142, 560144, 560156, C07C 6900

Patent

active

055875092

ABSTRACT:
A method of releasing a caged carboxylic acid in which a 2-alkoxy-5-nitro-phenyl photosensitive group blocks a carboxyl function and the compositions so produced are disclosed.

REFERENCES:
Billington et al., "Synthesis . . . Glycine Receptor", Biochemistry, vol. 31, pp. 5500-5507.
Kuzmic et al., "Photochemical hydrolysis of some nitrophenyl acetates", (abstract only), Collect. Czech. Chem. Commun., 1986, 51(6), pp. 1293-1300.
Wilcox et al., "Synthesis of Photolabile `Precursors` of Amino Acid Neurotransmitters", J. Org. Chem., 1990, vol. 55, No. 5, pp. 1585-1589.
Marquet et al., "The Search for Biochemical Photoprobes . . . ", Tetrahedron, vol. 49, No. 6, 1993, pp. 1297-1306.
Ninomiya et al., "Nonlinear Optical Organic Material and its Device", (abstract only), Jpn. Kokai Tokkyo Koho JP 04,166,819, 12 Jun. 1992., from Chem. Abstracts, vol. 117, p. 732, 1992.
Mizzoni et al., "Quinolines, Isoquinolines, and other 6-membered Rings", (abstract only), Chem. Abstracts, vol. 70, pp. 318-319, 1969.
Billington et al., "Synthesis and Photochemistry of Photolabile N-Glycine Derivatives . . . ", Biochemistry, vol. 31, No. 24, pp. 5500-5507, 1992.
Ramesh et al., "Photolysis of a Protecting Group for the Carboxyl Function . . . ", Proc. Natl. Acad. Sci. USA, vol. 90, No. 23, pp. 11074-11078, 1993.

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