Cage complexes for charge direction in liquid toners

Radiation imagery chemistry: process – composition – or product th – Electric or magnetic imagery – e.g. – xerography,... – Process of making developer composition

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G03G 9135

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active

055298753

ABSTRACT:
Disclosed are negatively and positively charged liquid toners for eleotrophotography (EP). The charge on the toner particle is obtained by adding cage complex molecules, or clathrates/cryptates, to the liquid toner. The cage complex molecules have at least three chains, with a least one electron pair donor atom in each chain, for a total of at least three electron pair donor atoms (EPD's). Or, the cage complex molecules have at least two connected rings, with a total of at least three EPD's in the molecule including at least one EPD in each of the connected rings. For negatively charged toner particles, the clathrates/cryptates are distributed in the liquid dispersion, and metal cations are weakly associated with anionic functional groups on the toner particle. This way, the clathrates/cryptates in dispersion complex selectively with the cations and strip them from the toner particle, leaving a negatively charged particle. For positively charged toner parities, the clathrates/cryptates are covalently bound to the toner particles, and weakly associated metal cations are added with corresponding anionic species to the liquid dispersion. This way, the clathrates/cryptaes on the toner particles complex selectively with the cations, and strip them from the dispersion, creating a positively charged particle.

REFERENCES:
patent: 4564574 (1986-01-01), Uytterhoeven et al.
patent: 4639404 (1987-01-01), Uytterhoeven et al.
patent: 5393635 (1995-02-01), Russell et al.
patent: 5411833 (1995-05-01), Swidler

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