Butane isomerization in the presence of C.sub.5 and C.sub.6 hydr

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By isomerization

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C07C 513

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active

048779199

ABSTRACT:
Butane is isomerized in the presence of substantial quantities of C.sub.5 and C.sub.6 hydrocarbons using an alumina catalyst having from 0.01 to 0.25 wt. % platinum and 2 to 10 wt. % of a chloride component. The process operates at temperatures ranging from 180.degree.-225.degree. C. (355.degree.-435.degree. F.) and produces a high yield of isobutane while at the same time providing a high level of C.sub.5 and C.sub.6 hydrocarbon isomerization without a significant increase in yield loss of C.sub.5 and higher hydrocarbons. The process can be carried out in a single reaction zone or in a series of reaction zones to increase the production of isoparaffins.

REFERENCES:
patent: 2939896 (1960-06-01), Myers
patent: 3112351 (1963-11-01), Hoekstra
patent: 3242228 (1966-03-01), Riordan et al.
patent: 3789082 (1974-01-01), Cook et al.
patent: 4113789 (1978-09-01), Rao et al.
patent: 4333856 (1982-06-01), Antos

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