Bulky borate activations

Compositions – Compositions containing a single chemical reactant or plural... – Organic reactant

Reexamination Certificate

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C252S182180, C252S182290, C502S103000, C502S108000, C502S117000, C502S152000, C502S202000, C526S127000, C526S160000, C526S351000, C568S006000

Reexamination Certificate

active

07077977

ABSTRACT:
A discrete polyolefin catalyst activator is disclosed. A salient feature of invention borate-based activators is that at least one of the ligands on the borate non-coordinating anion (NCA) comprises a fluorinated aryl group linked to the boron atom through an acetylenic group appropriate pairing of invention activators with olefin polymerization. Catalyst precursors yield increased catalytic activity. Polymerization results are disclosed.

REFERENCES:
patent: 4871705 (1989-10-01), Hoel
patent: 5198401 (1993-03-01), Turner et al.
patent: 5278119 (1994-01-01), Turner et al.
patent: 5278264 (1994-01-01), Spaleck et al.
patent: 5296433 (1994-03-01), Siedle et al.
patent: 5447895 (1995-09-01), Marks et al.
patent: 5502017 (1996-03-01), Marks et al.
patent: 6255531 (2001-07-01), Fritz et al.
patent: 6300450 (2001-10-01), Tsujimoto et al.
patent: 6391989 (2002-05-01), Bohnen et al.
patent: 6541410 (2003-04-01), Rodriguez
patent: 6774253 (2004-08-01), Resconi
patent: 6872844 (2005-03-01), Vogel
patent: 6909008 (2005-06-01), Rodriguez
patent: 2002/0082161 (2002-06-01), Vogel
patent: 0 277 003 (1987-01-01), None
patent: 0 277 004 (1987-01-01), None
patent: 824 113 (1997-08-01), None
patent: 0 811 627 (1997-12-01), None
patent: 97/29845 (1997-08-01), None
patent: WO 99/42467 (1999-08-01), None
Ahlers et al., “Dynamic Features of the Zirconocene-Boron=betaine complexes obtained by treatment of bis(alkynyl) zirconocenes with the tris(pentafluorophenyl) borane Lewis-acid,” Journal of Organometallic Chemistry, vol. 527, No. 1, pp. 191-201, (Jan. 11, 1997).
Kropp et al., “Photochemistry of Alkynyl-, Alkenyl-, and Cyclopropyl-Substituted Borate Salts: The Di-π-and Cyclopropyl-π-borate Rearrangements”, J. Am. Chem. Soc., vol. 113, pp. 2155-2163 (1991).
Baird et al., J. Am. Chem. Soc. vol. 116, pp. 6435-6436 (1994).
Strauss, Steven. “The Search for Larger and More Weakly Coordinating Anions,” Chem. Rev. vol. 93, pp. 927-942 (1993).
Han et al., “Tetraorganogallate Complexes in Organic Chemistry: A Novel, Efficient and Versatile Preparation of Ketones from Acyl Chlorides”, Tetrahedron Letters, Elsevier Science Publishers, Amsterdam, NL, vol. 36, No. 8, pp. 1287-1290 (Feb. 20, 1995).

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