Bulk synthesis of long nanotubes of transition metal...

Chemistry of inorganic compounds – Selenium or tellurium or compound thereof – Binary compound

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C423S561100, C423S565000, C423S566100

Reexamination Certificate

active

06841142

ABSTRACT:
Nanotubes of transition metal chalcogenides as long as 0.2-20 microns or more, perfect in shape and of high crystallinity, are synthesized from a transition metal material, e.g. the transition metal itself or a substance comprising a transition metal such as an oxide, water vapor and a H2X gas or H2gas and X vapor, wherein X is S, Se or Te, by a two-step or three-step method including first producing nanoparticles of the transition metal as long as 0.3 microns, and then annealing in a mild reducing atmosphere of the aforementioned gas or gas mixture. The transition metal chalcogenide is preferably WS2or WSe2. Tips for scanning probe microscopy can be prepared from said long transition metal chalcogenide nanotubes.

REFERENCES:
patent: 4055630 (1977-10-01), McCoy et al.
patent: 4299892 (1981-11-01), Dines et al.
patent: 4390514 (1983-06-01), Chianelli et al.
patent: 4548800 (1985-10-01), Badesha et al.
patent: 4676969 (1987-06-01), Smith
patent: 5958358 (1999-09-01), Tenne et al.
patent: 0 580 019 (1994-01-01), None
patent: WO 9744278 (1997-11-01), None
patent: WO 9823796 (1998-06-01), None
Y. Feldman et al., “High-Rate, gas-Phase Growth of MoS2Nested Inorganic Fullerenes and Nanotubes”,Science,Jan. 13, 1995, pp. 222-225, vol. 267.
Y. Feldman et al., “Bulk Synthesis of Inorganic Fullerene-like MS2(M=Mo, W) from the Respective Trioxides and the Reaction Mechanism”,Journal of the American Chemical Society,1996, pp. 5362-5367, vol. 118, No. 23.
M. Hershfinkel et al., “Nested Polyhedra of MX2(M=W, Mo; X=S, Se) Probed by High-Resolution Electron Microscopy and Scanning Tunneling Microscopy”,Journal of the American Chemical Society,1994, pp. 1914-1917, vol. 116.
M. Remskar et al., “MoS2as Microtubes”,Appl. Phys. Lett.,Jul. 15, 1996, vol. 69, No. 3.
M. Remskar et al., “New Crystal Structures of WS2: Microtubes, Ribbons, and Ropes”,Adv. Mater.,1998, pp. 246-249, vol. 10, No. 3.
M. Remskar et al., “Stabilization of the Rhombohedral Polytype in MoS2and WS2Microtubes: TEM and AFM Study”,Surface Science,1999, pp. 637-641, vol. 435.
M. Remskar et al., “Syntactic Coalescence of WS2Nanotubes”,Applied Physics Letters,Jun. 14, 1999, pp. 3633-3635, vol. 74, No. 24.
R. Tenne et al., “Polyhedral and Cylindrical Structures of Tungsten Disulphide”,Nature,Dec. 1992, pp. 444-445, vol. 360.
C.M. Zelenski et al., “Template Synthesis of Near-Monodisperse1Microscale Nanofibers and Nanotubules of MoS2”,J. Am. Chem. Soc.,1998, pp. 734-742, vol. 120.
Ajayan, P.M. et al; “Carbon nanotubes as removable tamplates for metal oxide nanocomposites and nanostructures”;Nature,vol. 375, pp. 554-567, (no month).
Chopra, N.G. et al; “Boron Nitride Nanotubes”;Science;vol. 269; 1995; pp. 966-967, (no month).
Dai, H. et al; “Nanotubes as nanoprobes in scanning probe microscopy”;Nature;vol. 384; 1996; pp. 147-150, (no month).
Feldman, Y. et al; “Kinetics of Nested Inorganic Fullerene-like Nanoparticle Formation”;J. Am. Chem. Soc.;vol. 120; 1998, pp 4176-4183, (no month).
Frey, G.L; “Optical properties of MS2 (M=Mo, W) inorganic Fullerene-like and nanotube material optical absorption and resonance Raman measurements”;J. Mater Res.vol. 13, No. 9, 1998; pp. 2412-2417, (no month).
Glemser, O. “Zur Frage der Wolframblauverbindungen”;J. Mater.Res.1998; 13, 2412, (no month).
Hardcastle, F.D.; “Determination of the Molecular Structures of Tungstates by Raman Spectroscopy”;Journal of Raman Spectroscopy,vol. 26, 1995; pp. 397-405, (no month).
Horsley, J.A.; Structure of Surface Tungsten Oxide Species in the WO3/A1203 Supported Oxide System from X-ray Absorption Near-Edge Spectroscopy and Raman Spectroscopy;J. Phys. Chem.vol. 91, 1987; pp. 4014-4020, (no month).
Iguchi, E.; “Strain Energy Between CS Planes”;Journal of Solid State Chemistry;vol. 23, 1978; pp. 231-239, (no month).
Iijima, S. “Helical microtubules of Graphitic carbon”;Nature;vol. 354; 1991; pp. 56-58, (no month).
Margulis, L. “Nested fullerene-like structures”;Nature;vol. 365, 1993; pp. 113-114, (no month).
Miyano, T. et al; “High-Resolution Electron Microscopic Studies of CS Structure in Reduced WO3 Thin Crystals”;Japanese Journal of Applied Physics;vol. 22, 1983; pp. 863-868, (no month).
Sloan, J. et al; “Defect and Ordered Tungsten Oxides Encapsulated Inside 2H-WX2 (X=S and Se) Fullerene-Related Structures”;Journal of Solid State Chemistry,vol. 144, 1999; pp. 100-117, (no month).
Sloan, J. et al; “Effect of tip shape on surface roughness measurements from atomic force microscopy images of thin films”;J. Vac. Sci. Technol.B 13(2), 1995; pp. 344-349, (no month).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Bulk synthesis of long nanotubes of transition metal... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Bulk synthesis of long nanotubes of transition metal..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Bulk synthesis of long nanotubes of transition metal... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3423234

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.