Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1993-07-02
1994-12-06
Schofer, Joseph L.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526132, 526160, 5261692, 526281, 526308, C08F 462
Patent
active
053711580
ABSTRACT:
Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers
Polymers of polycyclic olefins, such as, for example, norbornene or tetracyclododecene, or copolymers of polycyclic olefins with cycloolefins and/or 1-olefins are obtained without ring opening, in high space-time yield, with a high cycloolefin incorporation rate and at industrially favorable polymerization temperatures, by bulk polymerization in which a catalyst is used which comprises an aluminoxane and a stereorigid chiral metallocene compound of an element from groups IVb to VIb, where the hydrocarbon radicals forming the sandwich structure are different.
REFERENCES:
patent: 4178424 (1979-12-01), Tenney et al.
patent: 5003019 (1991-03-01), Ishimaru et al.
patent: 5087677 (1992-02-01), Brekner et al.
Antberg Martin
Brekner Michael-Joachim
Osan Frank
Rohrmann Jurgen
Hoechst Aktiengesellschaft
Schofer Joseph L.
Wu David
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