Buffer layers to enhance the C-axis growth of Bi4Ti3O12 thin...

Semiconductor device manufacturing: process – Having magnetic or ferroelectric component

Reexamination Certificate

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C438S686000

Reexamination Certificate

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06921671

ABSTRACT:
A method of fabricating a ferroelectric thin film on an iridium-composite electrode in an integrated circuit device includes preparing a substrate; depositing an iridium-composite bottom electrode on the substrate; annealing the bottom electrode in a first annealing step; depositing a buffer layer on the bottom electrode, including depositing a layer of material taken from the group of materials consisting of HfO2, ZrO2, TiO2, LaOx, La—Al—O, Ti—Al—O, Hf—Al—O, Zr—Al—O, Hf—Zr—O, Zr—Ti—O, Hf—Ti—O, La—Zr—O, La—Hf—O, and La—Ti—O; annealing the buffer layer in a second annealing step; depositing a layer of Bi4Ti3O12, to a thickness of between about 20 nm to 500 nm, on the buffer layer; annealing the ferroelectric layer in a third annealing step; and completing the integrated circuit device.

REFERENCES:
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patent: 6236113 (2001-05-01), Zhang et al.
patent: 6288420 (2001-09-01), Zhang et al.
patent: 6630702 (2003-10-01), Zhang et al.
patent: 6759252 (2004-07-01), Zhang et al.
Kijima et al.,Preparation of Bi4Ti3O12thin films on Si(100)using Bi2SiO5buffer layer and its electric characterization, J. Appl. Phys. vol. 37, Pt 1, 9B, 5171 (1998).
Nakamura et al.,Preparation of C-axis-oriented Bi4Ti3O12thin films by metalorganic chemical vapor deposition, Jpn. J. Phys. vol. 32, 4086 (1993).

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