Bridged biphospholes and metallocenes prepared therefrom

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S172000, C526S126000, C526S352000, C526S348600, C526S169000, C556S014000, C556S020000, C556S021000, C556S022000, C556S023000, C556S052000, C502S103000, C502S208000, C502S210000, C502S213000, C568S012000

Reexamination Certificate

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06927262

ABSTRACT:
The invention relates to novel bridged biphosphole ligands according to the general formula:where R2, R3, R4are chosen from hydrogen, alkyl, aryl or silyl, R1is chosen from hydrogen, alkyl, aryl or halogen, R1possibly being replaced with a direct bond between the two phosphorus atoms and T is a divalent group. The invention also relates to metallocenes obtained from these ligands. These metallocenes are useful as catalytic components for the polymerization of olefins.

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