Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...
Reexamination Certificate
2005-01-11
2005-01-11
Lu, Caixia (Department: 1713)
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Plural component system comprising a - group i to iv metal...
C502S103000, C502S122000, C502S123000, C502S150000, C502S162000, C502S168000, C502S171000, C502S172000, C568S642000, C568S631000, C564S280000
Reexamination Certificate
active
06841502
ABSTRACT:
New ligands and compositions with bridged bis-aromatic ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
REFERENCES:
patent: 4297465 (1981-10-01), Smith
patent: 4971936 (1990-11-01), Wilson et al.
patent: 5064802 (1991-11-01), Stevens et al.
patent: 5093415 (1992-03-01), Brady, III et al.
patent: 5153157 (1992-10-01), Hlatky et al.
patent: 5318935 (1994-06-01), Canich et al.
patent: 5385993 (1995-01-01), Fujita
patent: 5453410 (1995-09-01), Kolthammer et al.
patent: 5599761 (1997-02-01), Turner
patent: 5616664 (1997-04-01), Timmers et al.
patent: 5985356 (1999-11-01), Schultz et al.
patent: 6030917 (2000-02-01), Weinberg et al.
patent: 6175409 (2001-01-01), Nielsen et al.
patent: 6214939 (2001-04-01), Shinozaki et al.
patent: 6239236 (2001-05-01), Morini et al.
patent: 6260407 (2001-07-01), Petro et al.
patent: 6262199 (2001-07-01), Ewen et al.
patent: 6294388 (2001-09-01), Petro
patent: 6306658 (2001-10-01), Turner et al.
patent: 6406632 (2002-06-01), Safir et al.
patent: 6436292 (2002-08-01), Petro
patent: 6454947 (2002-09-01), Safir et al.
patent: 6455316 (2002-09-01), Turner et al.
patent: 6461515 (2002-10-01), Safir et al.
patent: 6475391 (2002-11-01), Safir et al.
patent: 6489168 (2002-12-01), Wang et al.
patent: 6491816 (2002-12-01), Petro
patent: 6491823 (2002-12-01), Safir et al.
patent: 6508984 (2003-01-01), Turner et al.
patent: 6548026 (2003-04-01), Dales et al.
patent: 20020002256 (2002-01-01), Peterson
patent: 0 277 004 (1988-08-01), None
patent: 0 292 134 (1988-11-01), None
patent: 0 534 405 (1993-03-01), None
patent: 0 582 194 (1994-02-01), None
patent: 0 622 380 (1994-11-01), None
patent: 0 922 712 (1999-06-01), None
patent: WO 9407926 (1994-04-01), None
patent: WO 9411409 (1994-05-01), None
patent: WO 9803521 (1998-01-01), None
patent: WO 9905186 (1999-02-01), None
patent: WO 9906413 (1999-02-01), None
patent: WO 9942467 (1999-08-01), None
patent: WO 0009255 (2000-02-01), None
patent: WO 0198371 (2001-12-01), None
patent: WO 0202576 (2002-01-01), None
patent: WO 0236638 (2002-05-01), None
Patent Abstracts of Japan, vol. 2003, No. 01, Jan. 14, 2003 & JP 2002 280179 A (Canon Inc.), Sep. 2002 (Sep. 27, 2002) Abstract.
Patent Abstracts of Japan, vol. 1996, No. 12, Dec. 26, 1996 & JP 08 217775 A (Takasago Internat'l Corp.), Aug. 27, 1996 (Aug. 27, 1996) Abstract.
Patent Abstracts of Japan, vol., 1996, No. 09, Sep. 30, 1996 & JUP 08 134064 A (Takasago Internat'l Corp.), May 28, 1996 (May 28, 1996) Astract.
Cram et al.,J. Am. Chem. Soc.,vol. 103, 1981, pp. 6228-6232, XP002245914—The Whole Document.
Cram et al.,J. Org. Chem.,vol. 54, 1989, pp. 5460-5482, XP002245915—The Whole Document.
Cram et al.,J. Am. Chem. Soc.,vol. 107, 1985, pp. 3657-3668, XP002245916—The Whole Document.
Cram et al.,J. Am. Chem. Soc.,vol. 107, 1985, pp. 3645-3657, XP002245917—The Whole Document.
Cram et al.,J. Org. Chem.,vol. 50, 1985, pp. 1486-1496, XP002245918—The Whole Document.
Helgeson et al.,Acta Crystallographica,Section C: Crystal Structure Communications, vol. C56, No. 7, 2000, pp. 795-797, XP009012979—The Whole Document.
Knobler et al.,Journal of Inclusion Phenomena and Molecular Recognition in Chemistry,vol. 12, No. 1-4, 1992, pp. 341-360, XP009012984—The Whole Document.
UEDA et al.,J. Chem. Soc.,Chem Commun., No. 9, 1995, pp. 935-936, XP009012989—The Whole Document.
Cram et al.,J. Chem. Soc.,Chem. Commun., No. 5, 1982, pp. 301-304, XP009012987—The Whole Document.
Cram et al.,J. Chem. Soc.,Chem. Comm., No. 21, 1979, pp. 948-950, XP009012986—The Whole Document.
Chang et al., “Syntheses of New Lactones Containing Phenyl or Methyl Groups”,Kongop Hwahak, J. of Korean Ind.&Eng. Chemistry,vol. 9, No. 6, 1998, 842-845.
Applied Homogeneous Catalysis,Wiley-VCH, edited by B. Cornils and W.A. Herrmann: 2nd Ed., 2002 vol. 2, 740-747.
Applied Homogeneous Catalysis,Wiley-VCH, edited by B. Cornils and W.A. Herrmann: 2nd Ed. 2002 vol. 1, 213-273.
Arrowsmith et al., “Comparison Of The Polymerization Of Propene By Homogeneous And Heterogeneous Metallocene/MAO-Catalysts Under Different Polymerization Conditions,”Macromol. Chem. Phys.2001, 202, 2161-2167.
Bennett et al., “Catalytic Conjugate Addition Promoted By The Copper(1)-monothiobinaphthol System. Part 3.1Comparison Of Three Thiolate-based Catalytic Systems,”J. Chem. Soc., Perkin Trans. 1,1999, 3127-3132.
Bochmann et al., “Base-Free Cationic Zirconium Benzyl Complexes As Highly Active Polymerization Catalysts,”Organometallics,1993, 12, 633-640.
Brintzinger, et al., “Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts”,Angew. Chem. Int., Ed. Engl.,1995, vol. 34, pp. 1143-1170.
Britovsek, et al., “The Search For New-Generation Olefin Polymerization Catalysts: Life Beyond Metallocenes,”Angew. Chem. Int. Ed.1999, 38, 428-447.
Chemical Reviews,2000, 100, No. 4, “Frontiers in Metal-Catalyzed Polymerization” Entire issue.
Chen, et al., “Cocatalysts For Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure-Activity Relationships,”Chem. Rev.2000, 100, 1391-1434.
Coates, “Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts,”Chem. Rev.2000, 100, 1223-1252.
Deng et al., “Synthesis Of High-Melting, Isotactic Polypropene With C2- and C1-Symmentrical Zirconocenes,”Macromolecules1996, 29, 6371-6376.
Ewen et al., “Evaluation Of The Dimethylsilyl-Bis(2-Methyl-4-Phenyl-1-Indenyl) Ligand With Group 4 Triad Metals In Propene Polymerizations With Methylaluminoxane,”Macromol. Rapid Commun.,1998, 19, 71-73.
Fink et al., “Propene Polymerization With Silica-Supported Matallocence/MAO Catalysts,”Chem. Rev.2000, 100, 1377-1390.
Gibson et al., “Advances in Non-Metallocence Olefin Polymerization Catalysis”Chem. Rev.2003, 103, 283-315.
Hlatky, “Heterogeneous Single-Site Catalysts For Olefin Polymerization,”Chem. Rev.2000, 100, 1347-1376.
Klapars et al.,J. Am. Chem. Soc.2001, 123(31), 7727-7729.
Jordan, “Chemistry of Cationic Dicyclopentadienyl Group 4 Metal-Alkyl Complexes”,Adv. Organometallic Chem.,1991, vol. 32, pp. 325-153.
Kaminsky et al., “The Influence Of The Polymerization Process On The Product Properties Of Metallocence-Polypropene,”Chem. Eng. Technol.,2001, 24, 11, 1124-1128.
Kol et al.,J. Am. Chem. Soc. 2000,122, 43, 10706-10707.
LaPointe, et al.,J. Am. Chem. Soc.2000, 122, 39, 9560-9561.
Luongo,J. Appl. Polym. Sci.,3(1960) 302-309.
Pellecchia et al., “Single Insertion of α-Olefins into The Cationic Complex [Zr(CH2Ph)3]+Affording Isolable [Zr(CH2Ph)2(CH2CHRCH2Ph)]+Adducts: A Model For the Insertion Mechanism in Ziegler-Natta Polymerization,”Organometallics1994, 13, 298-302.
Pellecchia et al., “Synthesis, Crystal Structure, and Olefin Polymerization Activity of a Zwitterionic η6-Arene Zirconium Tris(hydrocarbyl),”J. Am. Chem. Soc.1993, 115, 1160-1162.
Pellecchia, et al., “A Novel η/Coordination Mode Of A Benzyl Ligand In A Cationic Zirconium Complex,”Organometallics1994, 13, 3773-3775.
Piers, et al. “New Bifunctional Perfluoroaryl Boranes: Synthesis and Reactivity of the ortho-Phenylene-Bridged Diboranes 1,2-(B(C6F5)2)2C6X4(X=H, F)”,J. Am. Chem. Soc.,1999, 121, 3244-3245.
Resconi, et al., “Selectivity In Propene Polymerization With Metallocenc Catalysts,”Chem. Rev.2000, 100, 1253-1345.
Schrock,Organometallics1999, 18, pp. 3649-3670.
Stanforth,Tetrahedron,1998, 54(3/4), 263-303.
Sundell,Polymer 37(1996) 3227-3231.
Takahashi et al., “An Expedient Route To Some Monoalkyl Ethers O
Boussie Thomas R.
Brümmer Oliver
Diamond Gary M.
Goh Christopher
LaPointe Anne M.
Lu Caixia
Symyx Technologies Inc.
LandOfFree
Bridged bi-aromatic ligands, catalysts, processes for... does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Bridged bi-aromatic ligands, catalysts, processes for..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Bridged bi-aromatic ligands, catalysts, processes for... will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-3426171