Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Reexamination Certificate
2006-08-15
2006-08-15
Lu, Caixia (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
C526S131000, C526S161000, C526S348000, C568S013000, C568S017000, C568S018000, C568S585000, C568S642000, C568S705000, C568S718000, C502S162000, C502S167000, C502S168000
Reexamination Certificate
active
07091292
ABSTRACT:
Ligands, compositions, metal-ligand complexes and arrays with substituted bridged bis-biaromatic ligands, and methods of making and using the same, are disclosed that are useful in the catalysis of transformations such as the polymerization of monomers into polymers. The catalysts have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, propylene or styrene. The catalysts also polymerize propylene into isotactic polypropylene.
REFERENCES:
patent: 4297465 (1981-10-01), Smith
patent: 4971936 (1990-11-01), Wilson et al.
patent: 5064802 (1991-11-01), Stevens et al.
patent: 5093415 (1992-03-01), Brady, III et al.
patent: 5153157 (1992-10-01), Hlatky et al.
patent: 5318935 (1994-06-01), Canich et al.
patent: 5385993 (1995-01-01), Fujita
patent: 5453410 (1995-09-01), Kolthammer et al.
patent: 5599761 (1997-02-01), Turner
patent: 5616664 (1997-04-01), Timmers et al.
patent: 5985356 (1999-11-01), Schultz et al.
patent: 6030917 (2000-02-01), Weinberg et al.
patent: 6175409 (2001-01-01), Nielsen et al.
patent: 6214939 (2001-04-01), Shinozaki et al.
patent: 6239236 (2001-05-01), Morini et al.
patent: 6260407 (2001-07-01), Petro et al.
patent: 6262199 (2001-07-01), Ewen et al.
patent: 6294388 (2001-09-01), Petro
patent: 6306658 (2001-10-01), Turner et al.
patent: 6406632 (2002-06-01), Safir et al.
patent: 6436292 (2002-08-01), Petro
patent: 6454947 (2002-09-01), Safir et al.
patent: 6455316 (2002-09-01), Turner et al.
patent: 6461515 (2002-10-01), Safir
patent: 6475391 (2002-11-01), Safir et al.
patent: 6489168 (2002-12-01), Wang et al.
patent: 6491816 (2002-12-01), Petro
patent: 6491823 (2002-12-01), Safir et al.
patent: 6508984 (2003-01-01), Turner
patent: 6548026 (2003-04-01), Dales et al.
patent: 6713577 (2004-03-01), Boussie
patent: 6759014 (2004-07-01), Dales et al.
patent: 6841502 (2005-01-01), Boussie et al.
patent: 6869904 (2005-03-01), Boussie et al.
patent: 6897276 (2005-05-01), Boussie et al.
patent: 2002/0002256 (2002-01-01), Peterson
patent: 0 277 004 (1988-08-01), None
patent: 0 292 134 (1988-11-01), None
patent: 0 534 405 (1993-03-01), None
patent: 0 582 194 (1994-02-01), None
patent: 0 622 380 (1994-11-01), None
patent: 0 922 712 (1999-06-01), None
patent: 1 110 930 (2001-06-01), None
patent: 8-134064 (1996-05-01), None
patent: 08134064 (1996-05-01), None
patent: 8-217775 (1996-08-01), None
patent: 08217775 (1996-08-01), None
patent: 2002280179 (2002-09-01), None
patent: WO 94/07926 (1994-04-01), None
patent: WO 94/11409 (1994-05-01), None
patent: WO 98/03521 (1998-01-01), None
patent: WO 99/05186 (1999-02-01), None
patent: WO 99/06413 (1999-02-01), None
patent: WO 99/42467 (1999-08-01), None
patent: WO 00/09255 (2000-02-01), None
patent: WO 01/00581 (2001-01-01), None
patent: WO 01/48028 (2001-07-01), None
patent: WO 01/98371 (2001-12-01), None
patent: WO 02/02576 (2002-01-01), None
patent: WO 02/36638 (2002-05-01), None
patent: WO 02/083306 (2002-10-01), None
patent: WO 02/085820 (2002-10-01), None
Brintzinger et al., 1995, vol.: 34, pp.: 1143-1170, Angew. Chem. Int. Ed. Engl., Stereospecific Olefine Polymerization With Chiral Metallocene Catalysts.
Gibson et al., 1999, vol.: 38, pp.: 428-447, Angew. Chem. Int. Ed. Engl., The Search For New-Generation Olefin Polymerization Catalysts: Life Beyond Metallocenes.
Jordan, 1991, vol. 32, pp.: 325-387, Adv. Organometallic Chem., Chemistry Of Cationic Dicyclopentadienyl Group 4 Metal-Alkyl Complexes.
LaPointe, 2000, vol.: 122, pp.: 9560-9561, J. Am. Chem. Soc., New Family Of Weakly Coordinating Anions.
Plers et al., 999, vol.: 121, pp.: 3244-3245, J. Am. Chem. Soc., New Bifunctional Perfluoroaryl Boranes: Synthesis And Reactivity Of The Ortho-Phenylene-Bridged Diboranes . . .
Cram et al., 1981, vol.: 103, pp.: 6228-6232, J. Am. Chem. Soc., Augmented And Diminished Spherands And Scales of Binding.
Cram et al., 1985, vol.: 107, pp.: 3657-3668, J. Am. Chem. Soc., Host-Guest Complexation. 36. Spherand And Lithium and Sodium Ion Complexation Rates And Equilibria.
Cram et al., 1985, vol.: 107, pp.: 3645-3657, J. Am. Chem. Soc., Host-Guest Complexation. 35. Spherands The First Completely Preorganized Ligand SYstems.
Helgeson et al., 2000, vol.: 56, pp.: 795-797, Acta Cryst., The Lithium Chloride Complex Of The Anti Isomer Of The Bridged Sherand C50H48O6.
Knobler et al., 1992, vol.: 12, pp.: 341-360, J. Incl. Phen. & Molec. Recog. In Chem, The Crystal And Molecular Structures Of Bridged Spherands.
Ueda et al., 1995, Volume: pp.: 935-936, J.Chem Soc, Doubly Helical, Chiral Crown Thioether Fully Preorganized For Planner Coordination.
Cram et al., 1979, Volume: pp.: 948-950, J.C.S. Chemm Commun, A Spherand Containing An Enforced Cavity That Selectively Binds Lithium And Sodium Ions.
Schrock et al., Aug. 12, 1999, vol.: 18, pp.: 3649-3670, Organometallics, Synthesis of Titanium, Zirconium, and Hafnium Complexes that Contain Diamido Donor Ligands of the Type [(t-BuN-o-C6H4)2O]2 . . .
Coates, 2000, vol.: 100, pp.: 1223-1252, Chem Rev., Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts.
Deng et al. 1996, vol.: 29, pp.: 6371-6376, Macromolecules, Synthesis of High-Melting, Isotactic Polypropene with C2- and C1-Symmetrical Zirconocenes.
Resconi et al., 2000, vol.: 100, pp.: 1253-1345, Chem Rev., Selectivity in Propene Polymerization with Metallocene Catalysts.
Cornils et al., 2002, vol.: 2, pp.: 740-747, Applied Homogeneous Catalysts, Applied Homogeneous Catalysts.
Cornils et al., 2002, vol.: 1, pp.: 213-273, Applied Homogeneous Catalysts, Applied Homogeneous Catalysts.
Arrowsmith et al., 2001, vol.: 202, pp.: 2161-2167, Macromol. Chem. Phys., Comparison of the Polymerization of Propene by Homogeneous and Heterogeneous Metallocene/MAO-Catalysts Under Different Polymerization Conditions.
Bennett et al., 1999, vol.: 1, pp.: 3127-3132, J. Chem. Soc., Perkins Trans., Catalytic Conjugated Addition Promoted by the Copper(sup)1(sup)-monothiobinaphthol System. Part 3. (sup)1(sup) Comparison of Three Thiolate-based Catalytic Systems.
Bochmann et al., 1993, vol.: 12, pp.: 633-640, Organometallics, Base-Free Cationic Zirconium Benzyl Complexes as Highly Active Polymerization Catalysts.
Chang et al., 1998, vol.: 9 (6), pp.: 842-845, J. Korean Ind. & Eng. Chemistry, Syntheses of New Lactones Containing Phenyl or Methyl Groups.
2000, vol.: 100 (4), Pages: Entire issue, Chem Rev., Frontiers in Metal-Catalyzed Polymerization.
Chem et al., 2000, vol.: 100, pp.: 1391-1434, Chem Rev., Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure-Activity Relationships.
Ewen, 1998, vol.: 19, pp.: 71-73, Macromol. Rapid Commun., Evaluation of the Dimethylsilyl-Bis(2-Methyl-4-Phenyl-1-Indenyl) Ligand with Group 4 Triad Metals in Propene Polymerizations with Methylaluminoxane.
Fink, 2000, vol.: 100, pp.: 1377-1390, Chem Rev., Propene Polymerization with Silica-Supported Metallocene/MAO Catalysts.
Gibson et al., 2003, vol.: 103, pp.: 283-315, Chem Rev., Advances in Non-Metallocene Olefin Polymerization Catalysis.
Hlatky, 2000, vol.: 100, pp.: 1347-1376, Chem Rev., Heterogeneous Single-Site Catalysts for Olefin Polymerization.
Klapars et al., 2001, vol.: 123 (31), pp.: 7727-7729, J. Am. Chem. Soc., A General and Efficient Copper Catalyst for the Amidation of Aryl Halides and the N-Arylation of Nitrogen Heterocycles.
Kaminsky et al., 2001, vol.: 24 (11), pp.: 1124-1128, Chem. Eng. Technol., The Influence of the Polymerization Process on the Product Properties of Metallocene-Polypropene.
Kol et al., 2000, vol.: 122 (43) pp.: 10706-10707, J. Am. Chem. Soc., Isospecific Living Polymerization of 1-Hexene by a Readily Available Nonmetallocene C(sub)2(sub)-Symmetrical Zirconium Catalyst.
Luongo, 1960, vol.: 3, pp.: 302-309, J. Applied Polymer Science, Infrared Study of Polypropylene.
Pellecchia et al., 1994, vol.: 13, pp.: 298-302, Organometallics, Single Insertion of a-Olefins into the Cationic Complex [Zr(CH(sub)2(sub)Ph)(sub)3(sub)]+ Affording isotable [ZR(CH(sub)2(sub)Ph)(sub)2(sub)(CH(sub)2(
Bei Xiaohong
Boussie Thomas
Bruemmer Oliver
Diamond Gary M.
LaPointe Anne M.
Lu Caixia
Symyx Technologies Inc.
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