Branched hydroxy-terminated aliphatic polyethers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525403, C08G 6524, C08G 6532

Patent

active

048823953

ABSTRACT:
The invention disclosed is a process for the preparation of branched hydroxy-terminated aliphatic polyethers having alkyl azide substituents, having a structural formula ##STR1## and a molecular weight of abotu 500 to 40,000, and a process for the preparation thereof which comprises the single step of reacting a solid rubbery polyepichlorohydrin (PECH) of molecular weight of about 0.5-5.0.times.10.sup.6 with epichlorohydrin monomer (ECH) and an ionic azide selected from the group consisting of sodium azide, lithium azide and potassium azide, in a suitable organic solvent at elevated temperature, while agitating. According to a further aspect of the invention, the molecular weight of the polyether product may be controlled by adjusting the weight ratio of ECH:PECH, while maintaining a weight ratio of ionic azide: (ECH+PECH) of about 1:1.

REFERENCES:
patent: 3645917 (1972-02-01), Vandenberg
patent: 3971743 (1976-07-01), Breslow
patent: 4379894 (1983-04-01), Frankel et al.

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