Boron tris-(dialkyl-dithiocarbamates) and a process for their pr

Organic compounds -- part of the class 532-570 series – Organic compounds – Boron bonded directly to the single bonded x of a -c-x-...

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C07F 502

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active

049609335

ABSTRACT:
Boron tris-(dialkyl-dithiocarbamate) of the general formula ##STR1## wherein R and R' represent the same or different branched-or straight-chain saturated or unsaturated alkyl radicals having from 1 to 16 carbon atoms and a process for preparing the same, comprising reacting 3 moles of an alkali dialkyl-dithiocarbamate of the general formula ##STR2## wherein R and R' are as defined in claim 1 and Me.sup.+ represents Na.sup.+, K.sup.+ or NH.sub.4.sup.+ with one mole boron tribromide, boron trichloride or boron trifluoride in an inert medium, separating the so-formed alkali metal or ammonium halide and isolating the boron tris-(dialkyl-dithiocarbamate). The new boron dithiocarbamates are suitable as additives for hydraulic oils or permanent gear lubricant oils.

REFERENCES:
patent: 2862952 (1958-12-01), Groszos
patent: 2941000 (1960-06-01), May et al.
Cotton et al., "Advanced Inorganic Chemistry", Interscience Publishers, New York, N.Y., 1966, pp. 262-263 & 266-270.
Lalia-Kantouri et al., C.A., 88, 181,644y (1978).
Lalia-Kantouri et al., C.A., 84, 11648c (1976).

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