Boron-dipyrrin compounds comprising thienyl groups,...

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

Reexamination Certificate

active

08034930

ABSTRACT:
Disclosed are (i) a boron-dipyrrin compound having thienyl groups, (ii) a preparation method thereof and (iii) a chemosensor comprising the boron-dipyrrin compound having thienyl groups. More particularly, the present invention provides a boron-dipyrrin compound having thienyl group, furyl (OC4H3) group or selyl (SeC4H3) group, which is represented by the following formula (1), a preparation method thereof and a chemosensor comprising the above boron-dipyrrin compound having thienyl groups, characterized in that the chemosensor exhibits variations in colors and fluorescent properties caused by reaction of the boron-dipyrrin compound with metal ions, including, but not limited to, Cu2+and Hg2+:in-line-formulae description="In-line Formulae" end="lead"?3-(R)-4,4-di(R)-8-(R)-4-bora-3a,4a-diaza-s-indacene   formula (1)in-line-formulae description="In-line Formulae" end="tail"?wherein R is any one selected from 2-thienyl group and 3-thienyl group.

REFERENCES:
patent: 5248782 (1993-09-01), Haugland et al.
Choi et al., Inorganic Chemistry, 2007, 46(25):10564-10577.
Brückner, C., et al., “Synthesis of meso-phenyl-4,6-dipyrrins, preparation of their Cu(II), Ni(II), and Zn(II) chelates, and structural characterization of bis[mieso-phenyl-4,6-dipyrrinato]Ni(II)”, Can, J. Chem., vol. 74, pp. 2182-2193, (1996).
Qi, X. et al.,New BODIPY Derivatives as OFF—ON Fluorescent Chemosensor and Fluorescent Chemodosimeter for Cu2+: Cooperative Selectivity Enhancement toward Cu2+. Journal of Organic Chemistry 2006, 71, 2881-2884.
Rurack, K. et al.,A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuIIwith Virtually Decoupled Fluorophore and Receptor Units. Journal of the American Chemical Society 2000, 122, 968-969.
Coskun, A. et al.,Bis(2-pyridyl)-Substituted Boratriazaindacene as an NIR-Emitting Chemosensor for Hg(II). Organic Letters 2007, 9, 607-609.
Yuan, M. et al.,A Colorimetric and Fluorometric Dual-Modal Assay for Mercury Ion by a Molecule. Organic Letters 2007, 9, 2313-2316.
Moon, S.Y. et al.,New Hg2+-Selective Chromo- and Fuoroionophore Based upon 8-Hydroxyquinoline. Journal of Organic Chemistry 2004, 69, 181-183.
Lee, C. et al.,One-Flask Synthesis of Meso-Substituted Dipyrromethanes and Their Application in the Synthesis of Trans-Substituted Porphyrin Building Blocks. Tetrahedron 1994, 50, 11427-11440.
Littler, B.J. et al.,Refined Synthesis of 5-Substituted Dipyrromethanes. Journal of Organic Chemistry 1999, 64, 1391-1396.
Kee, H.L. et al.,Structural Control of the Photodynamics of Boron-Dipyrrin Complexes. Journal of Physical Chemistry B 2005, 109, 20433-20443.
Choi, S.H. et al.,X-ray diffraction, DFT, and spectroscopic study of N,N′-difluorobory1-5-(2-thienyl)dipyrrin and fluorescence studies of related dipyrromethanes, dipyrrins and BF2-dipyrrins and DFT conformational study of 5-(2-thienyl)dipyrrin. The Journal of Chemical Crystallography 2007, 37, 315-331.
Choi, S.H. et al.,Cu2+Colorimetric Sensing and Fluorescence Enhancement and Hg2+Fluorescence Diminution in “Scorpionate”-like Tetrathienyl-Substituted Boron-Dipyrrins. Inorganic Chemistry 2007, 46, 10564-10577.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Boron-dipyrrin compounds comprising thienyl groups,... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Boron-dipyrrin compounds comprising thienyl groups,..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Boron-dipyrrin compounds comprising thienyl groups,... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4296006

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.