Boron-containing ceramics through the chemical conversian of bor

Plastic and nonmetallic article shaping or treating: processes – Carbonizing to form article

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264 292, 264 296, 264 56, 264 82, 264 83, 2641761, 264183, 264204, 26421114, 26421119, 501 95, 501 96, 423291, D01F 908

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048328952

ABSTRACT:
A process for producing boron-containing ceramics such as boron carbide and boron nitride comprises pyrolyzing a blend of a precarbonaceous polymer such as polyacrylonitrile and a boron-containing polymer such as that formed by the reaction of a borane with a Lewis base. Pyrolyzation in an inert atmosphere yields boron carbide while pyrolyzation in a reactive gas burns away the precarbonaceous polymer and yiels a ceramic comprising the reaction product of boron and the pyrolyzation gas. Boron nitride ceramics are formed by pyrolyzing the preceramic blend in ammonia.

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