Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
1999-03-24
2002-05-28
Dawson, Robert (Department: 1712)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
C524S779000, C524S780000, C524S783000, C524S860000, C524S863000, C524S837000, C528S026000, C528S033000, C528S035000, C528S037000, C528S394000, C528S395000, C556S008000, C556S009000, C556S010000, C556S027000, C556S431000, C556S434000, C556S450000, C556S460000, C556S465000
Reexamination Certificate
active
06395826
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates to boron-and/or aluminum-containing, silicon-containing mixtures and hybrid materials and coatings produced therefrom.
German Patent Applications DE-A 19,603,242 and DE-A 19,603,241 and PCT Application WO 94/06807 describe numerous organosilanes from which inorganic-organic hybrid materials can be prepared via a sol-gel process. These materials can be employed, for example, for coating surfaces. The coatings, which can be cured at room temperature, are distinguished, for example, by a high transparency, good resistance to solvents, and good resistance to mechanical wear, with simultaneous elasticity. As a disadvantage, the mixtures described therein are not suitable for coating transparent substrates, such as plastic or glass, if these substrates are exposed to extreme mechanical stresses. For these materials, the wear resistance requirements are, of course, particularly high, since even the slightest damage impairs at least the visual impression. It was, therefore, desirable to improve the surface hardness of sol-gel coatings, in particular those based on the above-mentioned polyfunctional organosilanes, in order to be able to employ them in the coating of preferably transparent substrates.
The object of the present invention was, therefore, to provide mixtures based on monomeric polyfunctional organosilanes from which it is possible to produce coatings and for which the resistance to mechanical wear is significantly improved compared with the known systems and which are suitable for coating transparent substrates.
Surprisingly, it has now been found that the object can be achieved with the mixtures according to the invention of monomeric polyfunctional organosilanes and certain boron- and/or aluminum-containing compounds.
SUMMARY OF THE INVENTION
The present invention, therefore, relates to mixtures comprising
(A) at least one linear, branched, or cyclic monomeric organosilane having at least two silicon atoms with hydrolyzable and/or condensation-crosslinking groups, and at least one linking unit
(B) at least one boron-and/or aluminum-containing compound having the formula (I)
R
x
M(OR′)
3−x
(I)
wherein
M is Al or B,
x is0, 1,or 2,
R is C
1
-C
6
-alkyl, C
6
-C
12
-aryl, or (O)
½
, with the proviso that if R is (O)
½
, then the compound of the formula (I) is a chain when x is 1 and a cyclic or cage-form compound when x is 2, and
each R′ is independently H, C
1
-C
10
-alkyl, or C
6
-C
12
-aryl.
The invention further relates to hybrid materials prepared from such mixtures and to coatings produced therefrom.
REFERENCES:
patent: 5378790 (1995-01-01), Michalczyk et al.
patent: 5548051 (1996-08-01), Michalczyk et al.
patent: 5677410 (1997-10-01), Mager et al.
patent: 5962713 (1999-10-01), Kraus et al.
patent: 19603241 (1997-07-01), None
patent: 196 50 147 (1998-06-01), None
patent: 98/38251 (1998-09-01), None
Hawley, G.G. ed. 1971 “The Condensed Chemical Dictionary”, p. 782, 785.
Hofacker Steffen
Mager Michael
Dawson Robert
Gil Joseph C.
Henderson Richard E. L.
Robertson Jeffrey B.
Sloane Carolyn M.
LandOfFree
Boron-and/ or aluminum-containing mixtures, hybrid... does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Boron-and/ or aluminum-containing mixtures, hybrid..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Boron-and/ or aluminum-containing mixtures, hybrid... will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2826145