Stock material or miscellaneous articles – Composite – Of inorganic material
Reexamination Certificate
1999-09-15
2002-12-17
Yamnitzky, Marie (Department: 1774)
Stock material or miscellaneous articles
Composite
Of inorganic material
C428S691000, C428S917000, C313S504000, C313S506000, C257S040000, C257S103000, C252S301350, C526S220000, C526S242000, C526S256000, C526S259000, C526S280000, C526S315000, C528S244000
Reexamination Certificate
active
06495273
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to a new fluorinated tetraphenyl derivative, a new blue light-emitting polymer prepared using the tetraphenyl derivative as a monomer, an electroluminescence (EL) device manufactured using the polymer and a method for preparing or manufacturing the same. More particularly, the new fluorinated tetraphenyl derivative of the invention is represented as the formula (I) and allows the polymers prepared from it to be excellent in the ability of electron injection and transportation. The light-emitting polymer of the invention is represented as the formula (II) and is prepared by the reaction of the fluorinated tetraphenyl derivative with the compound allowing the polymer to be excellent in the ability of hole injection and transportation. The EL device of the invention is manufactured using the light-emitting polymer.
Here, A is —P(OR)
2
or —P
+
R′
3
, wherein R and R′ is an alkyl group or an aryl group.
Here, —Ar— is an arylene group.
DESCRIPTION OF THE PRIOR ART
Generally, as shown in
FIG. 1
, an EL device is formed by depositing, in turn, a transparent electrode
2
, a hole transport layer
3
, a polymer light-emitting layer and a metal electrode
6
on a substrate
1
. When the transparent electrode
2
and the metal electrode
6
are respectively connected to the (+) terminal and (−) terminal of a power supplier and power is supplied, holes are supplied to the polymer layer
4
through the transparent electrode
2
and hole transport layer
3
, electrons are also supplied to the polymer layer
4
through the metal electrode
6
and the electron transport layer
5
, and thereby, the holes and the electrons are combined in the polymer layer
4
to result in light emission.
Up to now, generally, &pgr;-conjugated polymers such as poly(1,4-phenylenevinylene) (PPV), poly(para-phenylene) (PPP) and polythiophene (PT) are mainly used as light-emitting materials of polymer electroluminescence (EL) devices. Such a &pgr;-conjugated polymer is excellent in the abilities of hole injection from the anode and the transport for the injected hole, but is not good in the abilities of electron injection from the cathode and the transport for the injected electron. The majority of the holes injected from the anode could not combine with the electrons injected from the cathode, which flow to the cathode. Therefore, the light emission efficiency of the EL device using the above polymer material as the emitting layer is very low, for the low combination probability of the holes with electrons.
For example, U.S. Pat. No. 5,247,190 discloses conductive polymers, poly(1,4-phenylenevinylene) and its derivatives as a light-emitting material.
U.S. Pat. No. 5,514,878 also discloses a method for enhancing the efficiency of a light-emitting device. In the patent document, the light-emitting device is manufactured using a light-emitting polymer containing a high electron affinity group, cyanide (CN) group and electrons are easily injected from the metal electrode (cathode) in the device, thereby, the combination probability of hole with electron is enhanced.
U.S. Pat. No. 5,376,456 also discloses a copolymer comprised of phenylenevinylene units and two benzene group containing units, wherein the benzene group is substituted with trifluoromethyl group.
However, the devices as described above are mostly not good in the electron injection and transport ability and thus, the holes injected from the anode flow to the cathode without combination with the electrons, that is, the combination probability of hole with electron is not sufficient.
Therefore, the device of the prior art is not sufficient in the light emission efficiency.
SUMMARY OF THE INVENTION
It is, therefore, an object of the present invention to provide fluorinated tetraphenyl derivatives and methods for preparing the same. Wherein the tetraphenyl derivative can be used as a monomer to prepare the light-emitting polymer excellent in electron injection and transport ability.
It is another object of the present invention to provide light-emitting polymers, with which the EL devices are excellent in electron injection and transport ability as well as in hole injection and transport ability and are light-emittable in the blue emission region, in which the EL device with inorganic material is not light-emittable. The light-emitting polymer of the invention is an alternated copolymer having, in alternated order, repeated units excellent in hole injection and transport ability and repeated units excellent in electron injection and transport ability. The present invention also provides methods for preparing the polymers.
It is also another object of the present invention to provide an EL device which is excellent in electron injection and transport ability as well as in hole injection and transport ability and is light-emittable in the blue emission region. The EL device of the invention is manufactured using the light-emitting polymer.
In accordance with one embodiment of the present invention, there are provided fluorinated tetraphenyl derivatives which are represented as the following formula (I).
Here, A is —P(OR)
2
or —P
+
R′
3
, wherein R and R′ is an alkyl group or an aryl group. Preferably, A is —P(OCH
2
CH
3
)
2
or —P
+
(C
6
H
5
)
3
.
In accordance with another embodiment of the present invention, there are provided light-emitting polymers which are represented as the following formula (II).
Here, —Ar— is an arylene group and n is 5-100. Preferably, —Ar— is selected from a group consisting
wherein R
1
, R
4
, R
5
, R
6
and R
7
are separately hydrogen or linear or branched C
1
~C
20
alkyl group having 1-20 carbons, and R
2
and R
3
are separately hydrogen or linear or branched alkyl or alkoxy group having 1-20 carbons.
In accordance with another embodiment of the present invention, there are provided EL devices containing a polymer light-emitting layer formed with the light-emitting polymer.
REFERENCES:
patent: 5247190 (1993-09-01), Friend et al.
patent: 5376456 (1994-12-01), Cumming et al.
patent: 5514878 (1996-05-01), Holmes et al.
patent: 6214481 (2001-04-01), Sakai et al.
Journal of Electronic Materials, Improved Efficiency in Green Polymer Light-Emitting Diodes with Air-Stable Electrodes, vol. 23, No. 6, 1994, pp. 453-458, (No month).
Letters to Nature, Light-emitting diodes based on conjugated polymers, vol. 347, Oct. 11, 1990, pp. 539-541.
Letters to Nature, Efficient light-emitting diodes on polymers with high electron affinities, vol. 365, Oct. 14, 1993, pp. 628-630.
Chu Hye Yong
Do Lee Mi
Hwang Do Hoon
Zyung Tae Hyoung
Blakely & Sokoloff, Taylor & Zafman
Electronics and Telecommunications Research Institute
Yamnitzky Marie
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