Block polymer preparation

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260879, C08L 906

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active

039594122

ABSTRACT:
Branched block copolymers are prepared by polymerizing a conjugated diene with or without a monovinyl substituted aromatic compound employing an organoalkalimetal initiator, coupling after substantially complete conversion with a reagent having at least two groups capable of combining with the polymer alkali metal moieties without terminating activity thereof, and thereafter adding a polymerizable monomer other than that employed in the first step.

REFERENCES:
patent: 3280084 (1966-10-01), Zelinski et al.
patent: 3624057 (1971-11-01), Farrar
patent: 3637554 (1972-01-01), Childers
patent: 3644322 (1972-02-01), Farrar
patent: 3692874 (1972-09-01), Farrar
patent: 3778490 (1973-12-01), Hsieh
patent: 3840616 (1974-10-01), Clark

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