Block copolymer surfactants prepared by stabilized free-radical

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525259, 525263, 525267, 525273, 525293, 525294, 525296, 525299, C08F29300, C08F29500

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active

061110256

ABSTRACT:
A block copolymer of a hydrophobic block of one or more hydrophobic monomers and a hydrophilic block of one or more hydrophilic monomers is prepared by polymerizing a hydrophobic monomer to prepare the hydrophobic block, using a free radical polymerization process using a stable free radical agent, preserving a stabilized active polymerization site on the hydrophobic block; adding a hydrophilic monomer to the stabilized active hydrophobic block; and further reacting the mixture to effect polymerization of the hydrophilic monomer. The polymerization of the hydrophilic monomer is conducted in an amidic solvent in which the hydrophobic block and the hydrophilic monomer are soluble.

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