Blister resistant pressure sensitive adhesive sheet

Stock material or miscellaneous articles – Web or sheet containing structurally defined element or... – Adhesive outermost layer

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525288, 525301, 526279, C09J 702

Patent

active

052523950

ABSTRACT:
A pressure sensitive adhesive sheet comprising a substrate and an adhesive composition which is coated on the surface of the substrate. The main components of the adhesive composition are (a) a copolymer comprising monomeric units of an acrylic ester, (b) monomeric units of a polar acrylic compound, (c) monomeric units of a high glass transition temperature (Tg) macromonomer having a Tg of 20.degree. C. or above, (d) monomeric units of a low Tg macromonomer having a Tg of below 20.degree. C. and (e) monomeric units of an oligomer having telechelic thiol functional groups. The pressure sensitive adhesive sheet has excellent adhesive strength, resistance against formation of blisters and removability upon heating.

REFERENCES:
patent: 3786116 (1974-01-01), Milkovich
patent: 3879494 (1975-04-01), Milkovich
patent: 4104330 (1978-08-01), Danzig
patent: 4551388 (1985-11-01), Schlademan
patent: 4693935 (1987-09-01), Mazurek
Mancinelli, "Macromonomers Lead to Acrylic Hot Melt and Solvent PSAs", Sep. 1985, pp. 17-21, Adhesives Age.
"Polymer Alloys", edited by Society of Polymer Science, Japan, Tokyo, Kagaku Dojin 1981, pp. 312-338 (and English language Abstract thereof).
Speical Edition: Functional Elastomers, Nippon Gomu Kyokaishi, vol. 59, 1986, pp. 331-339 (and English language Abstract thereof).

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