Bleed alleviation in ink-jet inks using organic acids

Compositions: coating or plastic – Coating or plastic compositions – Marking

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106 3149, 106 3158, 106 316, 106 3178, 106 3186, C09D 1102

Patent

active

057857431

ABSTRACT:
An organic acid component is employed in a first ink-jet ink composition to reduce the pH differential required to render insoluble the pH-sensitive colorant of a second encroaching ink-jet ink composition. By inducing the precipitation of the pH-sensitive colorant, migration of the colorant is inhibited, thereby substantially reducing bleed between the pH-sensitive ink and the ink containing the organic acid (the "target" ink). The organic acid component is employed at a concentration ranging from about 0.25 to 20 wt % and may be represented by such as acids as polyacrylic, acetic, glycolic, malonic, malic, maleic, ascorbic, succinic, glutaric, fumaric, citric, tartaric, lactic, sulfonic, ortho-phosphoric acid, derivatives thereof. Without the organic acid component, a pH differential on the order of at least 4 and more likely 5 units must exist between the pH-sensitive ink and the target ink to substantially eliminate bleed. By employing an organic acid in the practice of the invention, a pH differential on the order of only 1 to 3 units may be required. Therefore, assuming the pH-sensitive ink has a pH of about 8, the pH of the target ink could be as high as 7 in the practice of the invention as opposed to a pH of about 3 in the absence of an organic acid component.

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