Black alcohol soluble dye formulation

Details Black alcohol soluble dye formulation Black alcohol soluble dye formulation

2000-12-07

2003-12-23

Einsmann, Margaret (Department: 1751)

Bleaching and dyeing; fluid treatment and chemical modification

Organic additive for dye composition, dye composition...

Alcohol

C008S580000, C008S638000, C008S644000, C008S938000, C106S031010

Reexamination Certificate

active

06666897

ABSTRACT:

The present invention relates to black alcohol soluble dye formulations of high color intensity, low viscosity, and high tinctorial strength. The formulations are particularly useful for writing instruments such as felt tip and roller ball pens.
Inks formulated for use in writing instruments, as well as other printing applications such as ink jet printing, must be very fluid, stable, and free of any particles that could cause clogging of the instrument. In addition, such inks must be capable of depositing and adhering to the writing or printing substrate with a minimum of character blurring, must be fast drying, and should be permanent with respect to exposure to water. Such inks are generally formulated with soluble dye colorants in a compatible aqueous or solvent-based vehicle to form fluid, particle-free, dye solutions. Non-aqueous inks have advantages over aqueous-based inks since many solvent dyes have reasonable solubility in volatile organic solvents and, as a result, can be applied as true liquid solutions free of any particles. Another benefit of using solvent dyes in inks is that they tend to be permanent, at least with respect to exposure to water.
Writing instrument manufacturers often utilize solvent soluble inks for use as the color component for their finished ink formulations. Typically, such inks are a mixture or blend of a number of basic and/or solvent dyes. Black ink formulations are often customized to individual manufacturers' requirements to provide a multitude of shade variations from greyish to bluish black to convey company recognition by shade variations of the finished ink. This associates their pens to the end user. As a result, black dye formulations are typically blends of yellowish-brown dyes combined with black, violet, and/or blue dyes in widely varying ratios to achieve such shade variations.
The color component of any ink formulation is the controlling factor technically as well as economically. Stringent performance criteria, including light fastness, viscosity, surface tension, write out, etc., tend to limit the available choices for ink components, particularly the colorant. For these reasons, there is always a need in the industry for ink formulations which meet or exceed performance standards demanded by the industry and yet are more economical to use than those currently available.
We have discovered a black, solvent based dye formulation in which the amount of standard yellow-brown component is greatly reduced and yet which provides reduced formulation viscosity, increased tinctorial value without increasing the amount of colorant in the final ink formulation, allows inclusion of other dyes to modify the color and other solvents and co-solvents, and yet is more economical for the user.
The present invention, therefore, provides a black, alcohol soluble dye formulation composition comprising:
a) from 20 to 45 percent, preferably 30 to 45 percent, more preferably 39 to 41 percent, of a propanol solvent selected from n-propanol, isopropanol, or a mixture thereof;
b) from 30 to 35 percent, preferably 32 to 34 percent, more preferably 32 to 33 percent, of Nigrosine Base;
c) from 20 to 40 percent, preferably 23 to 35 percent, more preferably 23 to 26 percent, of one or more (C
7
-C
20
), preferably (C
8
-C
18
), more preferably (C
8
-C
10
), most preferably (C
8
) straight or branched chain, saturated or unsaturated carboxylic acids,
d) from 1 to 6 percent, preferably 2 to 5 percent, more preferably 2 to 3 percent, of a brown or yellow dye or combination thereof; and
e) from 1 to 3 percent, preferably 1 to 1.5 percent, more preferably 1 percent, of Crystal Violet Base, Methyl Violet Base, or mixture thereof; and
f) optionally, 0 to 5 percent, preferably 0 to 1 percent, of an ester cosolvent.
Unless otherwise specified herein, all percentages, parts, and ratios are by weight; are inclusive, and are combinable. All temperatures are in degrees Celcius and all temperature ranges are inclusive and combinable.
Preferably, the composition consists essentially of those components specified above. Preferably, the propanol solvent is n-propanol. Preferably, the carboxylic acid is 2-ethylhexanoic acid. Preferably the brown or yellow dye is selected from C.I. Solvent Brown 12 dye or a yellow dye of the formula:
as disclosed in U.S. Pat. No. 5,142,030, incorporated by reference herein, wherein each R is independently a (C
6
-C
12
)alkyl; preferably each R is a nonyl group (the xylene solution of which is available as Automate™ Yellow D dye from Morton International or Rohm and Haas Company), or a mixture thereof, most preferably the brown or yellow dye is C.I. Solvent Brown 12 dye. When used, the ester cosolvent is preferably an acetate, more preferably n-propyl acetate or ethyl acetate. Such cosolvents are most useful when the formulation is intended to be applied to a non-porous substrate.
The black solvent based formulations of this invention have high tinctorial strength. That is, these formulations have high spectral strength relative to their colorant concentrations. High tinctorial strength is important for certain applications such as ink jet printing. In addition, the compositions are highly fluid, that is, the viscosity is preferably less than 1200 centipoise (cP) at 25° C., more preferably less than 1000 cP, and essentially free of particles that can clog the dispensing tips of felt-tip and roller-ball pens as well as ink-jet printer heads. Also, when dried, the ink residue is permanent with respect to exposure to water but is resoluble with respect to its own solvent carriers. This prevents caking (drying) of the ink in the dispensing tips of felt-tip and roller-ball pens between uses. The inks are further capable of depositing and adhering to the printing substrate, preferably a porous substrate such as, for example, paper, cardstock, and corrugated cardboard, with a minimum of character fogging or bleeding and are fast drying without streaking and blotting on the substrate. In addition to use in writing instruments and ink-jet printers, the formulations of this invention may also be useful as wood stains, petroleum colorants, decorative coatings, and printing inks for the graphic arts industry.
Nigrosine dyes are a well-known class of black solvent dyes. The present invention concerns the use of solvent-soluble nigrosine dyes that are insoluble in water. Although there are water-soluble nigrosine dyes, particularly sulfonated nigrosines, this invention is not directed to their use. Water-soluble nigrosine dyes typically remain water-soluble in use and, therefore, can be washed away. Nigrosine dyes are obtained by heating nitro compounds, such as nitrobenzene or nitrophenols, with aniline and/or aniline hydrochloride in the presence of iron or ferric chloride. Different grades or types of nigrosine can readily be prepared by altering the proportions of the reactants and time of heating. The nigrosine compositions obtained from such processes are mixtures of compounds which, in their simplest form are of the formula:
Examples of commercially available nigrosine dyes include Solvent Black 5 and the free base form of Solvent Black 7 (“Nigrosine Base”):
Nigrosine Base is prepared by reaction of nigrosine dyes with mild alkalis, resulting in rearrangement.
Crystal Violet Base (C.I. Solvent Violet 9) and Methyl Violet Base (C.I. Solvent Violet 8) are classified as basic dye derivatives of pararosaniline, a triphenylmethane type dye. Solvent Brown 12 is a diazo dye mixture prepared by treatment of three parts of toluene-2,4-diamine hydrochloride with two parts of nitrous acid. Crystal Violet Base is preferred. Automate™ Yellow D is a yellow dye prepared by tetrazo coupling of 4,4′-diaminobenzanilide with 2 equivalents of p-nonyl phenol according to the procedure of U.S. Pat. No. 5,142,030, incorporated by reference herein.
Variations in the shade of black obtained with the formulations of this invention can be accomplished by varying the relative amounts of Nigrosine Base, the brown or yellow dye, and the Crystal or Methyl Violet Ba

Affiliated with

Also associated with

Rating

Black alcohol soluble dye formulation does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Black alcohol soluble dye formulation, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Black alcohol soluble dye formulation will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-3109095