Biuret purification

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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564 73, C07C12724, C07C12608

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active

046984437

ABSTRACT:
Purified biuret is recovered from mixtures containing biuret and higher molecular weight urea condensation products by contacting melts or solutions of such mixtures with a polar adsorbent and extracting biuret from the adsorbent with a polar desorbent. The useful biuret-containing mixtures also may contain urea. These methods are capable of recovering biuret of 99.9 percent plus purity from mixture containing higher molecular weight urea condensations products such as triuret, melamine, ammelide, and others. The biuret-containing desorbent can be recycled into contact with biuret-containing adsorbents to increase its biuret concentration, concentrated by evaporation of otherwise, and/or treated to crystallize biuret. An integrated process is provided which involves pyrolyzing urea to form biuret and higher molecular weight condensation products and selectively recovering biuret from the resulting pyrolyzed urea as described.

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