Bismuth oxide superconductor of preparing the same

Superconductor technology: apparatus – material – process – High temperature devices – systems – apparatus – com- ponents,... – Superconducting wire – tape – cable – or fiber – per se

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505236, 505701, 505704, 428689, 428701, 428702, 428930, H01L 3912

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active

056704593

ABSTRACT:
In a bismuth oxide superconductor having a composition of Bi-Sr-Ca-Cu or (Bi,Pb)-Sr-Ca-Cu and being covered with a metal sheath, the a-b plane of a 2223 phase, which is a 110 K phase, is oriented along the longitudinal direction as a matrix, while a dispersed superconducting phase mainly consisting of a 2212 phase, which is a 80 K phase, and/or non-superconducting phases is dispersed along the a-b plane in the 2223 phase, so that a magnetic field property of its critical current density is extremely improved. In order to prepare such a bismuth oxide superconductor, performed are the steps of preparing raw material which is based on a 2223 composition in Bi-Sr-Ca-Cu or (Bi,Pb)-Sr-Ca-Cu in relation to blending/composition, consisting as a superconducting phase of mainly a 2212 phase and non-superconducting phases in relation to the crystal structure, covering the raw material with a metal sheath, and performing deformation processing and heat treatment on the composite.

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patent: 5318948 (1994-06-01), Okada
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H. Sekine et al. "Fabrication of Bi-(Pb)-Sr-Ca-Cu-O mono-and multifilamentary superconductors and improvement in critical current density" vol. 66, No. 6, 15 Sep. 1989, New York US pp. 2762-2764.
P.V.P.S.S. Sastry et al. "Zero resistance at 120K in Bi(Pb)-Ca-Sr-Cu oxide" Physica C. vol. 157, No. 3, 1 Mar. 1989, Amsterdam NL pp. 491-494.
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