Bis-β-hydroxyethyl terephthalate production process...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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Reexamination Certificate

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10623002

ABSTRACT:
An aromatic polyester is pre-decomposed by heating together with bis-β-hydroxyethyl terephthalate and/or a low condensate thereof and then, reacted with ethylene glycol to convert the terephthalic acid component of the pre-decomposed product into bis-β-hydroxyethyl terephthalate and/or a low condensate thereof.The thus obtained solution composition, that is, bis-β-hydroxyethyl terephthalate solution composition containing ethylene glycol, bis-β-hydroxyethyl terephthalate and cations and/or anions as impurities is brought into contact with a cation exchanger and/or an anion exchanger to remove cations and anions as impurities to produce bis-β-hydroxyethyl terephthalate having a small content of ions.The bis-β-hydroxyethyl terephthalate-containing mixture having a small content of ions is subjected to preliminary evaporation or distillation to distill off a compound having a boiling point lower than that of bis-β-hydroxyethyl terephthalate and then, to evaporation or distillation under reduced pressure to give purified bis-β-hydroxyethyl terephthalate.Thus, purified bis-β-hydroxyethyl terephthalate having a cation and anion total content of 15 ppm or less is obtained.

REFERENCES:
patent: 145323 (1978-09-01), None
patent: 06166747 (1994-06-01), None
Patent Abstracts of Japan Publication No. 06-166747, published on Jun. 14, 1994 in the name of assignee Toray Ind. Inc. by inventors Morita Toru and Okasaka Hidesada entitled Depolymerization of Aromatic Polyester.

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