Bis-(silylethyl)-oligosulphides and process for their production

Details Bis-(silylethyl)-oligosulphides and process for their production Bis-(silylethyl)-oligosulphides and process for their production

1979-12-26

1983-10-04

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556429, C07F 708, C07F 718

Patent

active

044080646

ABSTRACT:
Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH.sub.2 .dbd.CH).sub.m -SiR.sub.n.sup.1 R.sub.4-(m+n) in which R represents chlorine, bromine, iodine, C.sub.1 -C.sub.3 -alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R.sup.1 represents C.sub.1 -C.sub.3 -alkyl, phenyl or C.sub.5 -C.sub.7 -cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100.degree. and 200.degree. C. under pressure of from 1 to 25 bars (total pressure at the reaction temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.

REFERENCES:
patent: 3530160 (1970-09-01), Gardner et al.
patent: 3686326 (1972-08-01), Oswald et al.
patent: 3768537 (1973-10-01), Hess et al.
patent: 3842111 (1974-10-01), Meyer-Simon et al.
patent: 3873489 (1975-03-01), Thurn et al.
patent: 3946059 (1976-03-01), Janssen et al.
patent: 3997581 (1976-12-01), Pletka et al.
patent: 4072701 (1978-02-01), Pletka et al.

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