Bis(bis-silylalkyl) dicarboxylates as adhesion promoters and com

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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556431, 528 15, 528 26, 528 29, C08F 704

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active

055502717

ABSTRACT:
Bis(bis-silylalkyl) dicarboxylates, especially maleates and fumarates, are prepared by a three-step process including esterification of malaic or fumaric acid or a functional derivative thereof with a branched dienol such as 1,6-heptadien-4-ol to form an alkadienol ester, reaction of the olefinic groups in said ester with a chlorosilane and alcoholysis of the chlorine atoms attached to silicon. The products are useful as adhesion promoters in addition curable polyorganosiloxane compositions.

REFERENCES:
patent: 3759968 (1973-09-01), Berger et al.
patent: 3780080 (1973-12-01), Berger et al.
patent: 3806532 (1974-04-01), Berger et al.
patent: 3808248 (1974-04-01), Berger et al.
patent: 5164461 (1992-11-01), Mitchell et al.

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