Bis(arylimino)acenaphthene nickel(II) complexes

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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564270, C07F 1502, C07C24900

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active

060020342

ABSTRACT:
Certain olefins such as ethylene, .alpha.-olefins and cyclopentene can be polymerized by using catalyst system containing a nickel or palladium .alpha.-diimine complex, a metal containing hydrocarbylation compound, and a selected Lewis acid, or a catalyst system containing certain nickel[II] or palladium[II] compounds, an .alpha.-diimine, a metal containing hydrocarbylation compound, and optionally a selected Lewis acid. The process advantageously produces polyolefins useful for molding resins, films, elastomers and other uses.

REFERENCES:
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patent: 5714556 (1998-02-01), Johnson et al.
PCT International Search Report for PCT/US 97/12801 (CR9969) dated Dec. 9, 1997.
Michael Svoboda and Heindirk tom Dieck, Diazadien-Nickel-Alkyle, Journal of Organometallic Chemistry, 191, 321-328, 1980.
Lynda K. Johnson, Christopher M. Killian, and Maurice Brookhart, New Pd(II)- and Ni(II)-Based Catalysts for polymerization of Ethylene and .alpha.-Olefins, J. Am. Chem. Soc., 117, 6414-6415, 1995.
Rob van Asselt, Cornelis J. Elsevier, Wilberth J. J. Smeets, Anthony L. Spek and Roland Benedix, Synthesis and characterization of rigid bidentate nitrogen ligands and some examples of coordination to divalent palladium. X-ray crystal structures of bis(.rho.-tolylimino)acenapthene and methylchloro[bis(o,o'-diisopropylphenylimino)acenaphthene]palladium(II), Recl. Trav. Chim. Pays-Bas, 113, 88-98, 1994.
Johnson et al., New Pd(II) and Ni(II)- Based Catalysts for Polymerization of Ethylene and Alpha-Olefins, J. Amer. Chem. Soc. 117, pp. 6414-6415, 1995.
van Asselt et al., Synthesis and Characterization of Rigid Bidentate Nitrogen Ligands and Some Examples of Coordination to Divalent Palladium, Recl. Trav. Chim. Pays-Bas. 113, pp. 88-98, 1994.
van Asselt et al., Insertion of Carbon Monoxide and Alkenes in Palladium-Carbon Bonds of Complexes Containing Rigid Bidentate Nitrogent Ligands, J. Amer. Chem. Soc. 116, pp. 977-985, 1994.

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