Bis-[aminophenyl ketones] compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Amino nitrogen containing

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549 13, 549 22, 549 74, 549357, 549496, C07C22522, C07D33904, C07D30702

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active

050720465

ABSTRACT:
This invention relates to a process for producing bis-[aminophenyl ketones] and the resulting compositions which are suitable for the preparation of engineering polymers, e.g., polyimides, polyurethanes and a host of other resinous materials. The bis-[aminophenyl ketones] are formed by reacting 2 moles of a nitrophenyl acid halide with an aromatic bridging composition having at least two hydrogen atoms of sufficient reactivity to undergo acylation reactions whereby nitrophenyl ketone groups are attached to the aromatic bridging group. The resulting bis-[nitrophenyl ketones] then are converted to the amine by hydrogenation or by double nucleophilic displacement with an aminophenol.
The invention also relates to polyimides and polyamides prepared from such bis-[aminophenyl ketones].

REFERENCES:
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patent: 4339568 (1982-07-01), Maresca
patent: 4393162 (1983-07-01), Paschke et al.
patent: 4657990 (1987-05-01), Daoust et al.
patent: 4663484 (1987-05-01), Horstmann
patent: 4687833 (1987-08-01), Clendinning et al.
Milto et al., Chem. Abstracts; vol. 111, No. 23; 214163q (1989).
Schoenberg et al., Chem. Abstracts; vol. 99, No. 10; 71346x (1983).
Hergenrother, P. M., Wakelyn, N. T., and Havens, S. J. "Polyamides Containing Carbonyl and Ether Connecting Groups" Journal of Polymer Science: Part A Polymer Chemistry, vol. 25, 1093-1103 (1987).

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