Bis(allyl carbonate) monomer and method for polymerizing same

Details Bis(allyl carbonate) monomer and method for polymerizing same Bis(allyl carbonate) monomer and method for polymerizing same

1986-05-01

1987-08-11

Michl, Paul R.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

5262305, 526314, C08F11000

Patent

active

046862668

ABSTRACT:
Fully cured, intact, solid castings of bis(allyl carbonate) resin, e.g., diethylene glycol bis(allyl carbonate), are prepared by polymerizing the resin with between about 0.75 and about 1.50 parts, per hundred parts of resin, of a monoperoxycarbonate, e.g., tertiarybutylperoxy isopropyl carbonate. An adhesion reducing amount, e.g., between about 25 and about 75 parts, per million parts of resin, of a mold release agent is incorporated into the liquid resin monomer to avoid cracking of the casting. Use of a mold release agent is not required when the resin is prepolymerized to about 15-20 percent allylic utilization.

REFERENCES:
patent: 2464062 (1949-03-01), Straw
patent: 3326859 (1967-06-01), Seiner
patent: 4590008 (1986-05-01), Tang et al.

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