Bipolar transistor and method manufacture thereof

Active solid-state devices (e.g. – transistors – solid-state diode – Heterojunction device – Bipolar transistor

Reexamination Certificate

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C257S191000, C257S200000, C257S592000

Reexamination Certificate

active

06828602

ABSTRACT:

TECHNICAL FIELD
The present invention relates to a hetero junction type bipolar transistor and a fabrication method thereof, and more particularly to a measure to improve a linearity of current characteristics.
BACKGROUND ART
Recently, the development has been advancing at a high pitch for a hetero bipolar transistor (HBT) that realizes an operation at a high frequency region with better conduction characteristics conferred by incorporating a hetero junction structure, such as Si/SiGe and Si/SiC, into a bipolar transistor fabricated on a silicon substrate. The HBT uses a Si/SiGe hetero junction structure obtained by allowing epitaxial growth of a SiGe layer on a Si substrate, so that it realizes a transistor operating at a high frequency region at which a conventional transistor cannot operate unless it uses a compound semiconductor substrate, such as GaAs. The HBT is made of materials having a good affinity for a general silicon process, such as a Si substrate and a SiGe layer, which provides remarkable advantages in achieving high integration and a low cost. In particular, integrating a HBT and a MOS transistor (MOSFET) by forming the both on a common Si substrate makes it possible to fabricate a high-performance BiCMOS device. Moreover, the BiCMOS device is expected to serve as a system LSI applicable to communication systems.
FIG. 10
is a cross section showing a structure of a conventional HBT. As is shown in the drawing, a top portion of a Si substrate
500
having a (
001
) plane forms a retrograde well
501
with a depth of 1 &mgr;m including a N-type impurity, such as phosphorous, introduced by the epitaxial growth method, ion implantation method, etc. Also, for the isolation, provided are a shallow trench
503
filled with silicon oxide and a deep trench
504
formed from an undoped polysilicon film
505
and a silicon dioxide film
506
surrounding the same. The trenches
503
and
504
have depths of approximately 0.35 &mgr;m and 2 &mgr;m, respectively.
Also, a collector layer
502
is provided in the Si substrate
500
at a region sandwiched by the trenches
503
, and a N+ collector connecting layer
507
is provided in the Si substrate
500
at a region separated from the collector layer
502
by the shallow trench
503
for establishing a contact with an electrode of the collector layer
502
through the retrograde well
501
.
Also, a first deposited oxide film
508
with a thickness of approximately 30 nm having a collector opening portion
510
is formed on the Si substrate
500
, and a Si/Si
1-x
Ge
x
layer
511
is formed by depositing a Si
1-x
Ge
x
layer doped with a P-type impurity with a thickness of approximately 60 nm and a Si film with a thickness of approximately 10 nm on the top surface of the Si substrate
500
at a portion exposed to the collector opening portion
510
. The bottom portion of the Si/Si
1-x
Ge
x
layer
511
at the center thereof (a region below a base opening portion
518
, which will be described bellow) functions as an intrinsic base
519
. On the other hand, the top portion of the Si/Si
1-x
Ge
x
layer
511
at the center thereof functions as an emitter layer.
A second deposited oxide film
512
with a thickness of approximately 30 nm to serve as an etch stopper is provided on the Si/Si
1-x
Ge
x
layer
511
and the first deposited oxide film
508
, and the second deposited oxide film
512
is provided with a base junction opening portion
514
and a base opening portion
518
. Provided next are a P+ polysilicon layer
515
with a thickness of approximately 150 nm that fills in the base junction opening portion
514
and extends over the second deposited oxide film
512
, and a third deposited oxide film
517
. An extrinsic base
516
is constructed by the Si/Si
1-x
Ge
x
layer
511
except for the region below the base opening portion
518
and the P+ polysilicon layer
515
.
Also, the P+ polysilicon layer
515
and the third deposited oxide film
517
are opened at portions positioned above the base opening portion
518
in the second deposited oxide film
512
, and a fourth deposited oxide film
520
with a thickness of approximately 30 nm is formed on the side surface of the P+ polysilicon layer
515
. Further, a sidewall
521
made of polysilicon with a thickness of approximately 100 nm is provided on the fourth deposited oxide film
520
. Then, an N+ polysilicon layer
529
is provided to fill the base opening portion
518
and to extend over the third deposited oxide film
517
, and the N+ polysilicon layer
529
thus functions as an emitter connecting electrode. The fourth deposited oxide film
520
not only electrically isolates the P+ polysilicon layer
515
from the N+ polysilicon layer
529
, but also prevents out-diffusion of the impurity from the P+ polysilicon layer
515
into the N+ polysilicon layer
529
. Also, the third deposited oxide film
517
electrically isolates the top surface of the P+ polysilicon layer
515
from the N+ polysilicon layer
529
.
Further, a Ti silicide layer
524
is formed on the surfaces of the collector connecting layer
507
, P+ polysilicon layer
515
, and N+ polysilicon layer
529
, and the outside sidewalls of the N+ polysilicon layer
529
and the P+ polysilicon layer
515
are covered with a sidewall
523
. The entire substrate is covered with an inter-layer insulator film
525
, through which contact holes that respectively reach the Ti silicide layer
524
formed on the N+ collector connecting layer
507
, P+ polysilicon layer
515
as a part of the extrinsic base, and N+ polysilicon layer
529
functioning as the emitter connecting electrode are provided. Then, each contact hole is filled with a W plug
526
and is provided with a metal wiring
527
connected to the W plug
526
and extending over the inter-layer insulator film
525
.
Problems to be Solved
However, the above-discussed conventional HBT or SiGe-BiCMOS has problems as follows.
FIG.
11
(
a
) is a view showing dependencies of a base current and a collector current on a base-emitter voltage, that is, so-called Gummel characteristics of the conventional HBT. In the drawing, the horizontal axis represents the base-emitter voltage (V), and the vertical axis represents the base current or collector current (A) (logarithmic scales). As is shown in the drawing, the parallel relation between the collector current characteristics curve and the base current characteristics curve is lost at a low base-emitter voltage region, and there is an excessive base current. In short, there is an inconvenience that the linearity of the current characteristics is deteriorated in the low bias region of the HBT.
Causes of such an inconvenience are checked, and one of the causes is found to be a recombination current generated excessively at a region underneath the second deposited oxide film
112
in the Si layer. It is assumed that such an excessive recombination current is generated because a depletion layer at the pn junction region in the Si layer is not formed in a satisfactory shape.
FIGS.
12
(
a
) and
12
(
b
) are an enlarged partial cross section showing an emitter-base junction region in the conventional HBT, and a doping profile of boron along a cross section in the vicinity of the emitter-base junction region, respectively. As shown in FIG.
12
(
a
), the Si/Si
1-x
Ge
x
layer
511
is formed by sequentially depositing an undoped SiGe spacer layer
551
with a Ge content of 15%, a P-type graded SiGe base layer
552
including boron at a high concentration with a Ge content continuously changing from 15% at the lower end to 0% at the upper end, and an undoped Si-cap layer
553
. The Si-cap layer
553
is provided with an N-type emitter diffusion layer
553
a
formed by introducing phosphorous out-diffused from the N+ polysilicon layer
529
(emitter connecting electrode) at a high concentration at a region directly below the base opening portion
518
and in contact with the N+ polysilicon layer
529
. Then, a perip

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