Biologically assisted process for treating sour gas at high pH

Chemistry of inorganic compounds – Sulfur or compound thereof – Elemental sulfur

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423220, 423224, 4235766, 4235767, 4235768, 423DIG17, 435168, 435266, B01D 5352, C01B 1705

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059895136

ABSTRACT:
A process for biologically enhancing an iron-based redox process for catalytic oxidation of a sulfide compound such as hydrogen sulfide from a gas in a redox system wherein said catalyst comprises a ferric compound and at least one organic chelant capable of holding ferric and ferrous ions in solution at processing temperatures and conditions suitable for generation and retrieval of elemental sulfur, comprising the steps of oxidation of a sulfide compound by a gas with a redox system comprising ferric ions, removal of elemental sulfur from said system, and reoxidation of ferrous ions in the redox system in the presence of a culture of bacteria comprising Thiobacillus ferrooxidans and leptospirillium ferrooxidans at a pH at least as high as about 7.5.

REFERENCES:
patent: 3218252 (1965-11-01), Glover et al.
patent: 3266889 (1966-08-01), Duncan et al.
patent: 3305353 (1967-02-01), Duncan et al.
patent: 4206288 (1980-06-01), Detz et al.
patent: 4455287 (1984-06-01), Primack et al.
patent: 4456688 (1984-06-01), Dugan et al.
patent: 4559313 (1985-12-01), Myerson et al.
patent: 4622212 (1986-11-01), McManus et al.
patent: 4666852 (1987-05-01), Cork
patent: 4758417 (1988-07-01), Van Lookeren-Campagne
patent: 4760027 (1988-07-01), Sublette
patent: 4789478 (1988-12-01), Revis et al.
patent: 4861723 (1989-08-01), Madgavkar
patent: 4888293 (1989-12-01), Hackl et al.
patent: 4891205 (1990-01-01), Bedell
patent: 4931262 (1990-06-01), Sonta et al.
patent: 4987081 (1991-01-01), Hackl et al.
patent: 5021069 (1991-06-01), Whellock et al.
patent: 5089412 (1992-02-01), Hackl et al.
patent: 5096691 (1992-03-01), Bedell
patent: 5338778 (1994-08-01), Bedell
patent: 5508014 (1996-04-01), Rai
patent: 5686293 (1997-11-01), Jenneman et al.
patent: 5747331 (1998-05-01), Hartikainen et al.
"Microorganisms in Reclamation of Metals" by Hutchins et al., Ann. Rev. Microbiol., 1986 No Month, vol. 40, pp. 311-335.
"Microbial Sweetening of Sour Gas," P.N. Agumadu and Charanjit Rai, 1991 GRI Liquid Redox Sulfur Recovery Conference, Austin, Texas, May 5-7, 1991, GRI 91/0188.
"Growth and Maintenance of Thiobacillus ferrooxidans Cells," Jean LaCombe Barron and Donald R. Lueking, pp. 2801, 2804, Applied and Environmental Microbiology, vol. 56 No. 9, Sep. 1990.
S.I.R. H1074, Lazaroff et al., Bacterio-Electric Leaching of Metals, Jul. 7, 1992.
"Studies on Bacteria In The ANG Stretford Plant," by Mary C. Bromel, Ph.D., Proceedings of the 1986 Stretford Users' Conference, Austin, Texas, May 5-6, 1986, pp. 176, 186, GRI 86/0256.
"Ferrous Iron Oxidation By Thiobacillus ferrooxidans," by W. John Ingledew, Biotechnology and Bioengineering Symp. No. 16, Workshop on Biotechnology for the Mining, Metal-Refining and Fossil Fuel Processing Industries, p. 24, 1986 No Month.
"Microbial Mining Boosts the Environment, Bottom Line," pp. 778, 779, Science, vol. 264, pp. 745-846, May 6, 1994 by Anne Simon Moffat.
"Early Experience With LO-CAT 11.TM. For Natural Gas Treatment," L.C. Hardison (ARI Technologies, Inc.), presented at AIChE Spring Meeting, Mar. 29-Apr. 2, 1992.
"Biologically-Enhanced Redox Solution Reoxidation" by C. Rai and J. Rao, Proceedings of the GRI 1994 Sulfur Recovery Conference, pp. 199-214, May 15-17, 1994.
"Bacteria Help Desulfurize Gas," H. Satoh, J. Yoshizawa and S. Kametanl, Hydrocarbon Processing, May 1988, pp. 76-D to 76-F.
"Microbial Sweetening of Sour Natural Gas Using Mixed Cultures," by Charanjit Rai and Martin Taylor, Environmental Progress, Spring, 1996. vol. 15 No. 1.
"Microbial Enhancement For Liquid Redox Systems--Data For A U.S. Patent Application, `An Improved Liquid Redox System Using Microbes,`" by Texas A&I University, Department of Chemical & Natural Gas Engineering, submitted to Gas Research Institute on Sep. 28, 1992.
"Processing and Utilization of High Sulfur Coals," edited by Yosry A. Attia, Coal Science and Technology 9, Proceedings of The First International Conference on Processing and Utilization of High Sulfur Coals, Oct. 13-17, 1985.
"Modelling of Fe.sup.2+ oxidation by Thiobacillus ferrooxidans," by Shrihari, R. Kumar, and K.S. Gandhi, Applied Microbiology and Biotechnology, (1990) 33:524-528.
"Microbial Sweetening of Sour Gas Using Acidophilic Chilean Cultures," by Ajay K. Singh and C. Rai, Texas A & M University, Paper No.: 18th, prepared for presentation at the 1995 Summer National Meeting of AIChE; Biotreating of Gas Streams, Jun., 1995.
"Recent Developments In Acid Gas Treatment Using The Autocirculation Lo-Cat(R) Approach," by L.C. Hardison, ARI Technologies, Inc., for presentation at the AIChE 1990 Spring National Meeting, Apr. 7-11, 1991.
"Case History--Lo-Cat.RTM. H.sub.2 S Oxidation System For Town Of Jupiter, Florida," by Robert F. Eaton, ARI Technologies, Inc., for presentation at GRI Liquid Redox Sulfur Recovery Conference, Oct. 4-6, 1992.
"Solutions to H.sub.2 S removal--The Town of Jupiter, Florida, Uses Lo-Cat.RTM. Unit to Solve Odor Problem in Water Treatment Plant," brochure by Wheelabrator Clean Air Systems Inc. Dec. 1992.
"Solutions to H.sub.2 S removal--Lo-Cat II.RTM. Unit Exceeds H.sub.2 S Removal Efficiency Requirements in Treatment of Wellhead Casing Gas," brochure by Wheelabrator Clean Air, Wheelabrator Technologies Inc. Dec. 1992.
"An Overview of Liquid Redox Sulfur Recovery," by D.A. Dalrymple, T.W. Trofe, and J.M. Evans, Chemical Engineering Progress, pp. 43-49, Mar., 1989.
"Technical and Economic Comparison of LO-CAT II.TM. with other Iron-Based Liquid Redox Processes," by M. P. Quinlan and L. W. Echterhoff, Paper presented at the 1992 GRI Liquid Redox Sulfur Recovery Conference in Austin, Texas, Oct. 4-6, 1992.
"Gas Research Institute Program in Sulfur Removal and Recovery Research--1992 Update," by D. Leppin, Proceedings of the 1992 Liquid Redox Sulfur Recovery Conference in Austin, Texas, Oct., 1992.
"LO-CAT II.TM.--A Big Step Forward in Iron Redox Chemistry," by Hardison Proceedings of the 1991 Liquid Redox Sulfur Recovery Conference in Austin, Texas, pp. 181-200, May, 1991.
"Kinetics of Liquid Phase Oxidation of Acid Ferrous Sulfate by the Bacterium Thiobacillus ferrooxidans," by D.T. Lacey and F. Lawson, Biotechnology and Bioengineering, vol. XII, Issue 1, pp. 30-50, 1987.
"Molecular Genetics of Thiobacillus ferrooxidans," by D.E. Rawlings and T. Kusano, Microbiological Reviews, vol. 58, No. 1, pp. 39-55, Mar., 1994.
"Process Optimization for Microbial Sweetening of Sour Natural Gas," by R.R. Gokarn , M.S. Thesis (Abstract), Texas A&I University, Aug. 1993.
"Iron Oxidation and Energy Conservation in Chemoautotroph Thiobacillus ferrooxidans," by John C. Cox and Martin D. Brand, Edited by W.R. Stroht and O.H. Touvinen, Microbial Chemoautotrophy, pp. 31-46, 1984.
"A Novel Microbial Sweetening Process for Sour Natural Gas Upgrading," by H.K. Dinesh-Mohan, M.S. Thesis (Abstract), Texas A&I University, 1992.
"Microbial Desulfurization of Coals in a Slurry Pipeline Reactor Using Thiobacillus ferrooxidans" by Charanjit Rai, Biotechnology Progress, vol. 1, No. 3, pp. 200-204, Sep. 1985.
"GRI Program in Sulfur Removal and Recovery from Natural Gas--1994 Update," by D. Leppin, Paper presented at GRI Sixth Sulfur Recovery Conference in Lakeway, Texas, May 15-17, 1994.
"Chelates' Role in Gas Treating," by S.A. Bedell, L.H. Kirby, C.W. Buenger and M.C. McGaugh, Hydrocarbon Processing, pp. 63-66, Jan., 1988.
"Application of Iron-Oxidizing Bacteria to Hydrometallurgical Flue Dust Treatment and H.sub.2 S Desulferization," by T. Shiratori and H. Sonta, FEMS Microbiology Reviews, 11, 1993, pp. 165-174.
"Microbial Mining Boosts the Environment, Bottom Line," by A. S. Moffat, Science, vol. 264, pp. 778-779, May 6, 1994.
"Mineral Biotechnology," by A. Bruynesteyn, Journal of Biotechnology, 11:1-10, 1989; Elsevier.
"Acidic Mine Drainage: the Rate Determining Step," by P.C. Singer and W. Stumm, Science, vol. 167, pp. 1121-1123, Feb. 1970.
"Desulfuring of Natural Gas and Petroleum Oil by Autotrophic Thiobacillus ferrooxidans," by Amitabha Das, Pradosh Roy, and Ajit K. Mishra, Letters in Applied Microbiology, 1993, vol. 16, 164-166.
"The Microbiology of Mine Drainage Polluti

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