Biocompatible macromers

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Peptide containing doai

Reexamination Certificate

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Details

C424S001210, C424S078080, C424S078170, C424S484000, C424S486000, C424S488000, C514S002600, C528S306000

Reexamination Certificate

active

06884778

ABSTRACT:
A new oligomer based on alternating fumaric acid and poly(ethylene glycol) (PEG) units is provided. The oligo(PEG fumarate) (OPF) may be functionalized by modification with a biocompatible organic group. Further, the OPF may be cross-linked using radical polymerization in the presence of either a chemical or photo initiator. A cross-linked OPF gel has a swelling behavior that is tunable dependent on the molecular weight of PEG. A cross-linkable PEG macromer, as exemplified by oligo(PEG fumarate), has unsaturated double bonds, for example in the fumaryl groups, along its macromolecular chain that allows for the preparation of hydrogels with tailored structure and properties.

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Jo et al., “Modificationof Oligo(poly(ethylene glycol) fumarate) Macromer with a GRGD Peptide for the Preparation of Functionalized Polymer Networks,” Biomacromolecules 2001, 2, 255-261.*
PCT International Search Report for International App. No. PCT/US01/14910: Dated Aug. 2, 2001; (4 p.).

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