Biocatalyst for the conversion of carbonyl compounds to their .b

Details Biocatalyst for the conversion of carbonyl compounds to their .b Biocatalyst for the conversion of carbonyl compounds to their .b

1997-08-25

1999-12-07

Shah, Mukund J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Four or more ring nitrogens in the bicyclo ring system

436518, 536529, C07D47500

Patent

active

059986166

ABSTRACT:
The present invention provides a general biocatalyst for transforming saturated carbonyl compounds to their .alpha.,.beta.-unsaturated analogs. The transformation is regio- as well as stereoselective. These catalysts are useful in the chiral resolution of carbonyl compounds as well as in the development of libraries of small molecules to screen as potential drug candidates.

REFERENCES:
patent: 4298735 (1981-11-01), Farina et al.
Murthy et al., "Syntheses and Applications of Flavine Analogs as Active Site Probes for Flavoproteins", Methods in Enzymology, vol. 280, 1997, pp. 436-460.
Murthy & Massey "Synthesis And Properties Of 8-CN-Flavins And Reconstituted Flavoproteins," Yerramilli V.S.N. Murthy & Vincent Massey, Department of Biological Chemistry, University of Michigan, Ann Arbor, MI, Abstract No. 046, 212.sup.th ACS National Meeting, mailed to public Aug. 8, 1996.

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