Binuclear rhodium complex as a hydroformylation and hydrogenatio

Details Binuclear rhodium complex as a hydroformylation and hydrogenatio Binuclear rhodium complex as a hydroformylation and hydrogenatio

1978-11-13

1980-07-29

Sneed, Helen M. S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252431P, C07F 1500

Patent

active

042150663

ABSTRACT:
The present invention relates to hydrogenation and hydroformylation catalysts based on a binuclear rhodium complex having the formula: ##STR1## wherein X and X' can be the same or different; when X and X' are the same they are organic tertiary phosphite groups and when different X is a CO group and X' is an organic tertiary phosphite group or an aromatic phosphine group, and SY and SY' are thiolato groups. The invention also comprises the processes of hydroformylation and hydrogenation using such catalytic complex.

REFERENCES:
patent: 3644447 (1972-02-01), Joshi
patent: 3794671 (1974-02-01), Wilkinson
patent: 3859359 (1975-01-01), Keblys
patent: 3890359 (1975-06-01), Chandra
patent: 3907847 (1975-09-01), Keblys
patent: 3956177 (1976-05-01), Luech

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