Compositions: coating or plastic – Coating or plastic compositions – Hydrocarbon containing
Reexamination Certificate
2000-06-28
2002-02-05
Brunsman, David (Department: 1755)
Compositions: coating or plastic
Coating or plastic compositions
Hydrocarbon containing
C106S181100, C106S182100, C106S190100, C106S191100, C106S196100, C106S311000, C501S094000, C501S109000, C501S119000, C264S630000, C264S631000, C264S664000, C419S065000
Reexamination Certificate
active
06344078
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention generally relates to a binder system for use in the field of forming ceramics or ceramic bodies and a method of producing ceramics or ceramic honeycomb bodies utilizing such a binder system. More particularly, the invention is concerned with a binder system that contains an organic liquid component and the use of that organic liquid-containing binder system in a method for producing ceramic honeycomb bodies
2. Discussion of the Related Art
Binders and binder systems useful for the manufacture of products from powdered materials, e.g., from particulate ceramic materials, must meet a number of requirements. For example, the binder and binder systems must be compatible with the ceramic material such that a flowable dispersion comprising a relatively high loading of the ceramic material in the binder may be provided. In addition, the “green” preform produced by shaping the dispersion of ceramic powder in the binder should have reasonable strength such that it can be handled.
For desirable “burnout” or removal of the binder, the binder should be removable from the shaped ceramic part without incurring distortion or breakage of the part. Furthermore, the binder-free preform should have at least a minimum level of strength, yet be sufficiently free of binder residues that defect-free consolidation is readily achievable.
The formulation of binders meeting these requirements is complex and a large number of different binder formulations have been disclosed in the prior art. Recently, cellulose ether binders have been favored for use in the forming articles of various shapes; i.e., honeycomb substrates. The mixtures are intimately blended and homogeneous and result in the green body having good integrity in size and shape, as well as uniform physical properties. In addition to the binders, these powder mixtures typically include certain organic additives, including for instance, surfactants, lubricants, and dispersants that function as processing aids to enhance wetting thereby producing a uniform batch.
Recently, there has been an increase in the demand for thinner walled, higher cell density cellular structures, complex shaped product, and products having a large frontal area. Thin walled and complex shaped products produced, utilizing the current binder technology, i.e., cellulose ether binders, are extremely difficult to handle without causing shape distortion because of the low strength of the “green” preform. One solution/recent trend in the extrusion technology, especially for multicellular honeycomb bodies, comprised of highly filled ceramic powder mixtures, is to extrude a stiffer body without causing a proportional increase in pressures. However, attempts to extrude stiffer ceramic batches with the current batch components; e.g., use of the aforementioned cellulose ether binder coupled with a lowering of the amount of water and/or including additives such as sodium tallowate or sodium stearate, have been largely unsuccessful because of the undesirable higher extrusion pressures and torques resulting from increased inorganic volume loading and increased abrasiveness of the batch.
Another attempted solution is to utilize rapid-setting techniques; i.e., solidifying the cell walls of the honeycomb quickly after forming, therefore ensuring that the dimension of the greenware will not be altered in subsequent cutting and handling steps. Prior rapid stiffening methods involve time-delayed stiffening using rapid set waxes as disclosed, for example in U.S. Pat. No. 5,568,652, and/or applying an external field such as an electrical, ultrasonic, or RF field at the die exit. Although these rapid-stiffening methods involve the extrusion of soft batches, which and historically, for highly filled ceramic mixtures, have lead to better extrusion quality, these methods have not been overly successful for thin walled cellular structures.
More recently, a solution has been disclosed in co-assigned U.S. Pat. App., Ser. No. 60/069,637 (Chalasani et al.) whereby the powder mixture, for forming honeycomb structures, includes powder materials, binder, solvent for the binder, surfactant, and a non-solvent (with respect to the binder, solvent and powder materials). This powder mixture is mixed, plasticized and shaped to form a green ceramic preform body having improved wet green strength and thus especially suitable for use in the processing of thin walled honeycomb structures. Furthermore, it is disclosed that the preferred aqueous binder system mixture includes water, cellulose ether and a hydrophobic non-solvent.
While this Chalasani reference provides significant advances in the capability of the art to form complex, thin-walled ceramic honeycomb bodies through extrusion, the inclusion of this non-solvent in the powder, e.g., light mineral oil, results in additional complications in the “burnout” or removal of the binder. Specifically, it is difficult to remove the binder components from the shaped ceramic part without incurring distortion or breakage of the part. Because of the reduced strength of the thin-wall ceramic honeycomb bodies and the corresponding increase in the dimensional changes during binder removal due to the exothermic nature of the removal of the oil, special considerations in the firing of the ceramic honeycomb must be undertaken to avoid cracking of the ceramic body. Specially designed kilns, apparatus for volatile removal, reduced oxygen containing atmospheres and increased, complicated firing cycles are among the numerous means that have been employed to reduce the differential shrinkage and high cracking frequency experienced during the firing of thin-walled ceramic honeycomb bodies which incorporate the aforementioned binder.
In light of the foregoing inconveniences experienced in the art, there remains a need to develop a binder system which permits a ceramic body to be formed and fired into a desired ceramic article without high differential shrinkage and incidences of cracking or defects and which can be quickly and easily removed from the ceramic body.
SUMMARY OF THE INVENTION
It is an therefore an object of the present invention to provide a binder system capable of use in forming ceramic or other inorganic honeycomb bodies which results in a sufficiently high wet strength of the formed green body with at least a portion of the binder system capable of being removed by evaporation during the drying process, thereby reducing the exotherms that can result in cracking and differential shrinkage during firing.
The above object of the invention may be achieved according to the invention that provides a binder system for use in the formation of ceramic or other powder-formed greenware. The essential components of the binder system of the invention include a binder, a solvent for the binder, a surfactant, and a component that is non-solvent with respect to any inorganic components, binder and solvent. The non-solvent component exhibits a lower viscosity than the solvent when containing the binder and comprises at least a portion of an organic liquid having a 90% recovered distillation temperature no greater than about 225° C. and more preferably less than about 220° C., as measured by, and defined in ASTM D86.
According to another embodiment of this invention, there is provided a moldable powder batch comprised of an inorganic powder component, consisting of a sinterable inorganic particulate material, and the above-mentioned binder system.
Preferred materials for use as the organic liquid in the binder system of the invention include, for example, straight and/or branched saturated and unsaturated hydrocarbons and/or cyclic hydrocarbons including aromatic or halogenated hydrocarbons exhibiting a carbon chain length having a distribution ranging from 8 to 14; most preferably, an isoparaffin and/or paraffin exhibiting a carbon chain length having a distribution ranging from 9 to 12.
According to another embodiment of the invention there is provided a method for forming and shaping plasticized powder mi
Beall Douglas M.
Chalasani Devi
Johnson Ronald E.
Brunsman David
Corning Incorporated
Schaeberle Timothy M.
Sterre Kees van der
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