Bifunctional anion-exchange resins with improved selectivity and

Liquid purification or separation – Processes – Ion exchange or selective sorption

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210682, 521 27, 521 30, 521 32, 521 34, 525381, C02F 142

Patent

active

060599758

ABSTRACT:
Disclosed herein are a class of anion exchange resins containing two different exchange sites with improved selectivity and sorptive capability for chemical species in solution, such as heptavalent technetium (as pertechnetate anion, TcO.sub.4.sup.-). The resins are prepared by first reacting haloalkylated crosslinked copolymer beads with a large tertiary amine in a solvent in which the resin beads can swell, followed by reaction with a second, smaller, tertiary amine to more fully complete the functionalization of the resin. The resins have enhanced selectivity, capacity, and exchange kinetics.

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